Abstract
The review considers methods of describing and preliminarily calculating the equilibrium characteristics of the adsorption of gases, vapors, and vapor-liquid mixtures of substances on adsorbents of different structures based on semiempirical, thermodynamic, and molecular models of adsorption systems. Based on the performed analysis, the systems of equations are obtained that allow one to fully describe the corresponding equilibriums and perform a theoretical study of highly selective adsorption systems for practically important engineering processes.
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Original Russian Text © A.M. Tolmachev, 2010, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2010, Vol. 46, No. 2, pp. 136–150.
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Tolmachev, A.M. Adsorption of gases, vapors, and solutions: I. Thermodynamics of adsorption. Prot Met Phys Chem Surf 46, 170–183 (2010). https://doi.org/10.1134/S2070205110020024
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DOI: https://doi.org/10.1134/S2070205110020024