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Experience in introducing a cobalt catalyst technology for the synthesis of hydrocarbons from CO and H2

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Abstract

The experience in introducing the technology of for the production of a silica-supported cobalt catalyst under industrial conditions is summarized. The catalyst is designed for the selective synthesis of С5+ hydrocarbons from СО and Н2, including macromolecular hydrocarbons С35+. The technology has been implemented at ZAO Samara Catalyst Factory. Parameters of the technological process are adjusted to allow for the features of existing equipment in preparing an experimental industrial lot of catalysts. The optimum technological mode of support preparation (evacuation to avoid granule cracking), its impregnation (at 80°С over 30 min), and the thermal treatment of the catalyst (in programmed mode at a maximum temperature of 400°С over a total of 9 h) are determined. The catalysts of an experimental industrial lot of 1 m3 conform to the new technical conditions in their physicochemical and catalytic properties.

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References

  1. Grigor’ev, D.A., Neft’ Gaz Biznes, 2011, no. 3, pp. 1–6.

    Google Scholar 

  2. Lapidus, A.L., Golosman, E.Z., and Strizhakova, Yu.A., Solid Fuel Chem., 2011, vol. 45, no. 3, pp. 175–178.

    Article  CAS  Google Scholar 

  3. Khimicheskaya entsiklopediya (Chemical Encyclopedia), Zefirov, N.S., Ed., Moscow: Bol’shaya Rossiiskaya entsiklopediya, 1998, vol. 5, p. 351.

  4. Savost’yanov, A.P., Narochnyi, G.B., Yakovenko, R.E., Bakun, V. G., and Zemlyakov, N. D., Catal. Ind., 2014, vol. 6, no. 4, pp. 292–297.

    Article  Google Scholar 

  5. Yakovenko, R.E., Narochnyi, G.B., Bakun, V.G., and Astakhov, A.V., Izv. Vyssh. Uchebn. Zaved., Severo- Kavkaz. Region, Tekhn. Nauki, 2014, no. 6, pp. 92–95.

    Google Scholar 

  6. Savost’yanov, A.P., Narochnyi, G.B., Yakovenko, R.E., Astakhov, A.V., Zemlyakov, N.D., Merkin, A.A., and Komarov, A.A., Catal. Ind., 2014, vol. 6, no. 3, pp. 212–217.

    Article  Google Scholar 

  7. Mukhlenov, I.P., Dobkina, E.I., and Deryuzhkina, V.I., Tekhnologiya katalizatorov (Technology of Catalysts), Leningrad: Khimiya, 1989.

    Google Scholar 

  8. Kheifets, L.I. and Neimark, A.V., Mnogofaznye protsessy v poristykh sredakh (Multiphase Processes in Porous Media), Moscow: Khimiya, 1982.

    Google Scholar 

  9. International Center for Diffraction Data (ICDD), PDF-2 Release 2012. wwwicddcom. Cited March 22, 2016.

  10. Lamberov, A.A., Gil’manov, Kh.Kh., and Busygin, V.M., Katal. Prom-sti, 2006, no. 3, pp. 12–16.

    Google Scholar 

  11. Ioffe, I.I. and Pis’men, L.M., Inzhenernaya khimiya geterogennogo kataliza (Engineering Chemistry of Heterogeneous Catalysis), Leningrad: Khimiya, 1972.

    Google Scholar 

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Authors and Affiliations

  1. Platov South Russian State Polytechnic University, Novocherkassk, 346428, Russia

    G. B. Narochnyi, R. E. Yakovenko, A. P. Savost’yanov & V. G. Bakun

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  1. G. B. Narochnyi
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  2. R. E. Yakovenko
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  3. A. P. Savost’yanov
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  4. V. G. Bakun
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Correspondence to G. B. Narochnyi.

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Original Russian Text © G.B. Narochnyi, R.E. Yakovenko, A.P. Savost’yanov, V.G. Bakun, 2016, published in Kataliz v Promyshlennosti.

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Narochnyi, G.B., Yakovenko, R.E., Savost’yanov, A.P. et al. Experience in introducing a cobalt catalyst technology for the synthesis of hydrocarbons from CO and H2 . Catal. Ind. 8, 139–144 (2016). https://doi.org/10.1134/S2070050416020070

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  • DOI: https://doi.org/10.1134/S2070050416020070

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