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Selective reduction of nitrogen oxides by hydrocarbons on hydrotalcite Co and Ni catalysts

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Abstract

Hydrotalcitelike Co-Al and Ni-Al catalysts of different compositions (with the atomic ratio M 2+/Al3+ = 0.5–3.0) were studied in the reaction of selective reduction of NO by propane, propylene, and n-decane in the presence of O2. The higher activity of the catalysts with M 2+/Al3+ = 0.5 is connected with high dispersity of Ni or Co cations stabilized by a significant amount of Al3+ ions. Propylene was shown to be the most efficient reducing agent for nitrogen oxide. The highest degree of conversion to the extent of 90–99% was attained at 400 and 420–440°C for Ni-Al and Co-Al samples, respectively. When propane and decane were used as reducing agents, the conversion of both catalysts was characterized by the volcano-shaped dependence on temperature due to the fact that the catalyst took part in the concurrent reaction of hydrocarbon (reducing agent) oxidation. Hydrotalcitelike materials are promising representatives of inexpensive bi- and multicomponent systems. The design strategy for new active catalysts for processes of purification of gas exhausts from NO x , that are stable in the presence of water and sulfur oxides, may be based on usage of hydrotalcites with modified ions introduced into them.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    V. F. Tret’yakov & A. G. Zakirova

  2. Institute of Catalysis, Bulgarian Academy of Sciences, Sofia, Bulgaria

    A. A. Spozhakina, M. V. Gabrovska & R. Edreva-Kardzhieva

  3. SABIC Chair in Catalysis, King Abdulaziz University, Jeddah, Saudi Arabia

    A. A. Spozhakina, M. V. Gabrovska & R. Edreva-Kardzhieva

  4. SABIC Chair in Catalysis, King Abdulaziz University, Jeddah, Saudi Arabia

    L. A. Petrov

Authors
  1. V. F. Tret’yakov
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  2. A. G. Zakirova
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  3. A. A. Spozhakina
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  4. M. V. Gabrovska
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  5. R. Edreva-Kardzhieva
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  6. L. A. Petrov
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Correspondence to V. F. Tret’yakov.

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Original Russian Text © V.F. Tret’yakov, A.G. Zakirova, A.A. Spozhakina, M.V. Gabrovska, R. Edreva-Kardzhieva, L.A. Petrov, 2010, published in Kataliz v Promyshlennosti.

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Tret’yakov, V.F., Zakirova, A.G., Spozhakina, A.A. et al. Selective reduction of nitrogen oxides by hydrocarbons on hydrotalcite Co and Ni catalysts. Catal. Ind. 2, 62–66 (2010). https://doi.org/10.1134/S2070050410010101

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  • DOI: https://doi.org/10.1134/S2070050410010101

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