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Photoluminescence of composition chemosensor films based on structured mesoporous silica and photonic crystal structures

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Abstract

Optical structured composition chemosensor films were obtained based on photonic crystal matrices with monodisperse spherical silica particles (MSSP) 190 to 245 nm in size which were saturated with a nanosol of silica particles modified by fluorescein. As a result, the MSSP surface is covered with nanofilms of mesoporous silica, which provides the photoluminescence (PL) of the material. The photonic crystal structure of the composition film amplifies PL in comparison with a mesoporous reference.

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References

  1. W. Stober, A. Fink, and E. Bohn, “Controlled Growth Monodisperse Silica Spheres in the Micron Size Range,” J. Colloid Interface Sci. 26, 62–69 (1968).

    Article  Google Scholar 

  2. D. V. Kalinin, V. V. Serdobintseva, A. I. Plekhanov, and V. F. Shabanov, “Nanocrystallization of Single-Crystal Opal Films and the Spectral Characteristic of Related Photonic Structures,” Dokl. Akad. Nauk 411(2), 178–181 (2006) [Dokl. Phys. 51 (11), 591–594 (2006)].

    Google Scholar 

  3. D. V. Kalinin, A. I. Plekhanov, V. V. Serdobintseva, and V. F. Shabanov, “Photon Heterostructures Based on Single-Crystal Opal Films,” Dokl. Akad. Nauk 413(3), 329–331 (2007) [Dokl. Phys. 52 (3), 139–141 (2007)].

    Google Scholar 

  4. D. V. Kalinin, V. V. Serdobintseva, and V. F. Shabanov, “Layer-by-Layer Step Growth Mechanism of Photonic-Crystal Opal Films Grown by the Moving-Meniscus Method,” Dokl. Akad. Nauk 420(2), 178–181 (2008) [Dokl. Phys. 53 (5), 249–252 (2008)].

    Google Scholar 

  5. D. V. Kalinin, V. V. Serdobintseva, and V. F. Shabanov, “Nature of Microcracks in Photonic-Crystal Opal Films Grown by the Moving-Meniscus Method,” Dokl. Akad. Nauk 420(5), 607–609 (2008) [Dokl. Phys. 53 (6), 298–300 (2008)].

    Google Scholar 

  6. R. Iler, Chemistry of Silica (Wiley, New York, 1979; Mir, Moscow, 1982), p. 1106.

    Google Scholar 

  7. V. V. Serdobintseva, D. V. Kalinin, and S. V. Vosel’, “The Forms of Colloid Silica Participating in the Formation of Noble Opal and the Mechanism of Silicifica-tion of Its Gel Structures,” Geol. Geofiz. 39(8), 1116–1120(1998).

    CAS  Google Scholar 

  8. J. Kron, G. Schottner, and K.-J. Deichmann, “Glass Design via Hybrid Sol— Gel Materials,” Thin Solid Films 392, 236–242(2001).

    Article  CAS  ADS  Google Scholar 

  9. E. O. Oh, R. K. Gupta, and C. M. Whang, “Effects of pH and Dye Concentration on the Optical and Structural Properties of Coumarin-4 Dye-Doped SiO2-PDMS Xerogels,” J. Sol-Gel Sci. Technol. 28, 279–288 (2003).

    Article  CAS  Google Scholar 

  10. I. Sokolov, Y. Y. Kievsky, and J. M. Kaszpurenko, “Self-Assembly of Ultrabright Fluorescent Silica Particles,” Small 3(3), 419–423 (2007).

    Article  CAS  PubMed  Google Scholar 

  11. P. Prosposito, M. Casalboni, F. Matteis, Q. M. Glas-beek, E. van Veldhoven, and H. Zhang, “IR-Lumines-cent Molecules in Hybrid Materials,” J. Sol— Gel Sci. Technol. 26, 909–913 (2003).

    Article  CAS  Google Scholar 

  12. F. de Matteis, P. Prosposito, F. Sarcinelli, M. Casalboni, R. Pizzoferrato, A. Furlani, M. V. Russo, A. Van-nucci, and M. Varasi, “Silica-Based Sol— Gel Films Optically Functionalized through Doping with Organic Molecules,” J. Non-Cryst. Solids 245, 15–19 (1999).

    Article  Google Scholar 

  13. V. V. Serdobintseva, D. V. Kalinin, A. P. Eliseev, and N. V. Sobolev, “Structured Chemosensor Films Based on Silica Nanoparticles Modified by Organic Colorants,” Dokl. Akad. Nauk 422(2), 236–238 (2008) [Dokl. Earth Sci. 422 (7), 1116–1118 (2008)].

    Google Scholar 

  14. Hong Yang, A. Kuperman, N. Coombs, S. Mamlche-Afara, and G. A. Ozin, “Synthesis of Oriented Films of Mesoporous Silica on Mica,” Nature (London) 379(22 February), 703–705 (1996).

    Article  CAS  ADS  Google Scholar 

  15. Hong Yang, N. Coombs, I. Sokolov, and G. A. Ozin, “Free-Standing and Oriented Mesoporous Silica Films Grown at the Air—Water Interface,” Nature (London) 381(13), 589–592 (1996).

    Article  CAS  ADS  Google Scholar 

  16. Hong Yang, N. Coombs, and G. A. Ozin, “Morphogenesis of Shapes and Surface Patterns in Mesoporous Silica,” Nature (London) 386(17), 692–695 (1997).

    Article  CAS  ADS  Google Scholar 

  17. N. D. Deniskina, D. V. Kalinin, and L. K. Kazantseva, Precious Opals (Nauka, Novosibirsk, 1987), p. 181 [in Russian].

    Google Scholar 

  18. D. V. Kalinin and V. V. Serdobintseva, “Deposits of Precious Opal: Genesis and Search Criteria,” Geol. Geofiz. 44(4), 340–347 (2003).

    CAS  Google Scholar 

  19. R. Frantz, C. Carbonneau, M. Granier, J. O. Durand, G. F. Lanneau, and R. J. Corrie, “Studies of Organic-Inorganic Solids Possessing Sensitive Oligoarylene—Vinylene Chromophore-Terminated Phosphonates,” Tetrahedron Lett. 43(1), 6569–6572 (2002).

    Article  CAS  Google Scholar 

  20. M. M. Collinson, “Recent Trend in Analytical Applications of Organically Modified Silicate Materials,” Trends Anal. Chem. 21(1), 30–38 (2002).

    Article  CAS  Google Scholar 

  21. Xi Chen, Yuan Dai, Zhen Li, Zhi Zhang, and Xiao Wang, “Optical Rubbery Ormosils Sensor for the Detection of Ammonia,” Fresenius’ J. Anal. Chem. 370, 1048–1051 (2001).

    Article  CAS  Google Scholar 

  22. E. Yablonovitch, “Inhibited Spontaneous Emission in Solid-State Physics and Electronics,” Phys. Rev. Lett. 58, 2059–2062 (1987).

    Article  CAS  PubMed  ADS  Google Scholar 

  23. S. G. Romanov, T. Maka, C. M. Sotomayor Torres, M. Müller, R. Zentel, D. Cassagne, J. Manzanares-Martinez, and C. Jouanin, “Diffraction of Light from Thin-Film Polymethylmethacrylate Opaline Photonic Crystals,” Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys. 63, 056 603 (5 pages) (2001).

    CAS  Google Scholar 

  24. S. G. Romanov, T. Maka, C. M. Sotomayor Torres, M. Müller, and R. Zentel, Photonic Crystals and Light Localization in the 21st Century, Ed. by C. M. Soukoulis (Kluwer, Dordrecht, The Netherlands, 2001) [NATO Ser. C 563, 253–262 (2001)].

    Google Scholar 

  25. A. V. Yakimanskii, A. Yu. Men’shikova, T. G. Evseeva, N. N. Shevchenko, and A. Yu. Bilibin, “Monodis-persed Polymer Particles with Covalently Attached Chromophore Groupings as Structural Elements of Protonic Crystals,” Ross. Nanotekhnol. 1(1–2), 183–190 (2006).

    Google Scholar 

  26. A. Yu. Men’shikova, N. N. Shevchenko, B. M. Shabsel’s, A. V. Sel’kin, A. G. Bazhenova, E. S. Anish-chenko, and A. V. Yakimanskii, “Self-Assembly of Monodispersed Polymer Particles into Protonic Crystals and Introduction of Chromophores into Them,” Ross. Nanotekhnol. 2(11–12), 84, 85 (2007).

    Google Scholar 

  27. D. V. Kalinin, V. V. Serdobintseva, and V. F. Shabanov, “A New Method for Building Photonic-Crystal Opal Films by Stacking Monodisperse Spherical Silica Particles into a Regular Structure in a Surfactant Medium,” Ross. Nanotekhnol. 4(5–6), 94–97 (2009) [Nano-technol. Russ. 4 (5–6), 359–365 (2009)].

    Google Scholar 

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Correspondence to D. V. Kalinin.

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Original Russian Text © D. V. Kalinin, V. V. Serdobintseva, A.P. Eliseev, 2010, published in Rossiiskie nanotekhnologii, 2010, Vol. 5, Nos. 1–2.

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Kalinin, D.V., Serdobintseva, V.V. & Eliseev, A.P. Photoluminescence of composition chemosensor films based on structured mesoporous silica and photonic crystal structures. Nanotechnol Russia 5, 130–136 (2010). https://doi.org/10.1134/S1995078010010131

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  • DOI: https://doi.org/10.1134/S1995078010010131

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