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Multiporous Silica Nanoparticles with Carbon Nanodots: Synthesis, Optoelectronic and Biomedical Applications

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Abstract

Spherical multiporous silica nanoparticles (MPSNs) with the diameter of 50 ± 15 nm containing two types of nanopores with the sizes of 0.8–2 nm (type I) and 5–10 nm (type II) inside are synthesized. The film formed from MPSNs contains pores with the size of 10–40 nm (type III) formed due to the packaging of spherical nanoparticles. Methods for the selective introduction of dye molecules of propidium iodide (PI), carbon nanodots (CDs) with the size of 3.5 nm, and Ag nanoparticles (20 nm) into pores of types I, II, and III, respectively, are developed. The possibility of using MPSN/CD and MPSN/CD/Ag films as luminophores for white light LEDs is shown. It is demonstrated that composite particles of MPSN/CD and MPSN/CD/PI are nontoxic and allow visualization of the cell structure (by the example of HeLa) simultaneously in several spectral ranges.

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ACKNOWLEDGMENTS

The authors are grateful to NainTekh LLC (Tolyatti, Russia) for the donated colloidal solution of silver nanoparticles. Transmission electron microscopy studies were performed using the equipment of the Federal Center for C-ollective Use “Materials Science and Diagnostics in Advanced Technologies.”

Funding

This study was supported by the Russian Foundation for Basic Research (project no. 18-29-19122mk).

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Authors and Affiliations

  1. Ioffe Institute, St. Petersburg, Russia

    D. A. Kurdyukov, D. A. Eurov, A. V. Medvedev, D. A. Kirilenko, M. V. Tomkovich & V. G. Golubev

  2. St. Petersburg Alferov National Research Academic University, St. Petersburg, Russia

    S. V. Shmakov

Authors
  1. D. A. Kurdyukov
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  2. D. A. Eurov
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  3. A. V. Medvedev
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  4. D. A. Kirilenko
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  5. M. V. Tomkovich
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  6. S. V. Shmakov
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  7. V. G. Golubev
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Corresponding author

Correspondence to D. A. Eurov.

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Translated by S. Rostovtseva

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Kurdyukov, D.A., Eurov, D.A., Medvedev, A.V. et al. Multiporous Silica Nanoparticles with Carbon Nanodots: Synthesis, Optoelectronic and Biomedical Applications. Phys. Solid State 63, 1704–1710 (2021). https://doi.org/10.1134/S1063783421100206

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  • DOI: https://doi.org/10.1134/S1063783421100206

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