Abstract
The structure, thermodynamical, and optical properties of 8–23-nm-thick polypyromellitimide nanolayers obtained on a semiconductor surface by spin-coating of prepolymer solutions and their consequent imidization at the temperatures up to 453 K have been investigated. It is found that decreasing the nanolayers’ thickness leads to a sharp decrease in their temperature and imidization time. It is shown that polyimide layers thinner than 10 nm on a semiconductor surface are not continuous; instead, they are self-organizing discontinuous coverings with typical sizes of polymer islets in a substrate plane of around hundreds of nanometers in size. The possibility of using the above-mentioned continuous and discontinuous nanolayers of a semiconductor surface as aligning surfaces for liquid crystals to be used in the production of flexible displays has been proven.
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Original Russian Text © E.S. Kuz’menko, A.A. Zhukov, E.P. Pozhidaev, I.N. Kompanets, 2010, published in Rossiiskie nanotekhnologii, 2010, Vol. 5, Nos. 1–2.
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Kuz’menko, E.S., Zhukov, A.A., Pozhidaev, E.P. et al. Nanolayers of polypyromellitimide aligning surfaces of liquid crystals for organic electronics devices. Nanotechnol Russia 5, 123–129 (2010). https://doi.org/10.1134/S199507801001012X
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DOI: https://doi.org/10.1134/S199507801001012X