Abstract
For the first time, it has been shown that the rate of the catalytic decomposition of ammonia over (C2B10H4) n organoboron nanoparticles can be controlled via generating an electric potential of different polarity and magnitude on the particles using an external voltage source. At a temperature of 700 K, a pressure of 10–6 Torr, and a positive potential of the particles of +6 V, the decomposition rate increases by 26%, while at a negative potential of–6 V, it decreases by 37% compared to the decomposition rate of ammonia at a zero potential of the particles.
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Original Russian Text © M.V. Grishin, A.K. Gatin, V.G. Slutskii, V.A. Kharitonov, S.A. Tsyganov, B.R. Shub, 2016, published in Khimicheskaya Fizika, 2016, Vol. 35, No. 6, pp. 85–89.
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Grishin, M.V., Gatin, A.K., Slutskii, V.G. et al. Effect of the electric potential of organoboron nanoparticles on their catalytic activity in the decomposition of ammonia. Russ. J. Phys. Chem. B 10, 538–542 (2016). https://doi.org/10.1134/S1990793116030192
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DOI: https://doi.org/10.1134/S1990793116030192