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Effect of space charge on the ion mobility spectrum with two close lines

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Abstract

In ion mobility spectrometers, space-charge field has a significant effect on the diffusion and drift of ions, if the initial ion density is higher than 106 cm−3. Owing to this effect, the ion distribution in time and space cannot be described by a Gaussian curve any longer. These non-Gaussian ion distributions change the shape of the spectra not only quantitatively, but also qualitatively, which can lead to a misinterpretation of the spectra.

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References

  1. G. A. Eiceman and Z. Karpas, Ion Mobility Spectrometry (CRC Press, Boca Raton, USA, 2005).

    Book  Google Scholar 

  2. A. A. Schvartsburg, Differential Ion Mobility Spectrometry (CRC Press, Boca Raton, USA, 2009).

    Google Scholar 

  3. J. I. Baumbach and G. A. Eiceman, Appl. Spectrosc. 53, 338 (1999).

    Article  Google Scholar 

  4. A. V. Tolmachev, B. H. Clowers, M. E. Belov, and R. D. Smith, Anal. Chem. 81, 4778 (2009).

    Article  CAS  Google Scholar 

  5. H. H. Hill, Jr., W. F. Siems, and R. H. St. Louis, Anal. Chem. 62, 1201A (1990).

    Article  CAS  Google Scholar 

  6. G. A. Eiceman, Crit. Rev. Anal. Chem. 22, 471 (1991).

    Article  CAS  Google Scholar 

  7. D. Jones, A. G. Brenton, D. E. Games, et al., Rapid Commun. Mass Spectrom. 7, 561 (2005).

    Article  Google Scholar 

  8. S. Marcus, A. Mend, L. Shore, et al., Theriogenology 78, 753 (2012).

    Article  CAS  Google Scholar 

  9. E. V. Krisilova, A. M. Levina, and V. A. Makarenko, J. Anal. Chem. 69, 371 (2014).

    Article  CAS  Google Scholar 

  10. F. Furche, R. Ahlrichs, P. Weis, et al., J. Chem. Phys. 117, 6982 (2002).

    Article  CAS  Google Scholar 

  11. P. Weis, O. Welz, E. Vollmer, and M. Kappes, J. Chem. Phys. 120, 677 (2004).

    Article  CAS  Google Scholar 

  12. K. Koyasu, T. Ohtaki, and F. Misaizu, Bull. Chem. Soc. Jpn. 84, 1342 (2011).

    Article  CAS  Google Scholar 

  13. J. A. McLean, L. S. Fenn, and J. R. Enders, Methods Mol. Biol. 656, 363 (2010).

    Article  CAS  Google Scholar 

  14. M. L. Glasser, J. Appl. Phys. 63, 4823 (1988).

    Article  Google Scholar 

  15. G. E. Spangler, Anal. Chem. 64, 1312 (1992).

    Article  CAS  Google Scholar 

  16. J. Xu, W. B. Whitten, and J. M. Ramsey, Anal. Chem. 72, 5787 (2000).

    Article  CAS  Google Scholar 

  17. J. Xu, W. B. Whitten, and J. M. Ramsey, US Patent No. 6822225 (2004).

    Google Scholar 

  18. G. E. Spangler, Anal. Chem. 82, 8052 (2010).

    Article  CAS  Google Scholar 

  19. A. V. Mariano, W. Su, and S. K. Guharay, Anal. Chem. 81, 3385 (2009).

    Article  CAS  Google Scholar 

  20. A. V. Tolmachev, B. H. Clowers, M. E. Belov, and R. D. Smith, Anal. Chem. 8181, 4778 (2009).

    Article  Google Scholar 

  21. V. Ilbeigi and M. Tabrizchi, Anal. Chem. 84, 3669 (2012).

    Article  CAS  Google Scholar 

  22. M. N. Levin, A. V. Krisilov, B. A. Zon, and G. A. Eiceman, Int. J. IMS. (2014, in press). doi:10.1007/s12127-014-0151-y

    Google Scholar 

  23. G. A. Korn and T. M. Korn, Mathematical Handbook for Scientists and Engineers (McGraw-Hill, New York, 1968).

    Google Scholar 

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Authors and Affiliations

  1. ZAO Innovation Center Biryuch, EFCO Group of Companies, Malobykovo, Belgorod oblast, Russia

    M. N. Levin

  2. Voronezh Institute of Government Communications, Branch of the Academy of the Federal Security Service of the Russian Federation, Voronezh, Russia

    A. V. Krisilov

  3. Voronezh State University, Voronezh, Russia

    B. A. Zon

Authors
  1. M. N. Levin
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  2. A. V. Krisilov
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  3. B. A. Zon
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Corresponding author

Correspondence to A. V. Krisilov.

Additional information

Original Russian Text © M.N. Levin, A.V. Krisilov, B.A. Zon, 2014, published in Khimicheskaya Fizika, 2014, Vol. 33, No. 12, pp. 60–64.

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Levin, M.N., Krisilov, A.V. & Zon, B.A. Effect of space charge on the ion mobility spectrum with two close lines. Russ. J. Phys. Chem. B 8, 888–892 (2014). https://doi.org/10.1134/S1990793114110207

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  • DOI: https://doi.org/10.1134/S1990793114110207

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