Abstract
The results of studies of the thermal and microwave-assisted expansion of graphites oxidized with acids are presented. The expansion of oxidized graphites heated to 180–300°C for up to 30 min or exposed to microwave radiation for 3–60 s is demonstrated to be of stepwise character. The bulk density of oxidized graphites as a function of thermal expansion conditions and microwave irradiation duration is determined. The results of studies on the thermal expansion of polymer-oxidized graphite composite materials are reported. Optical microscopy is used to monitor changes in the mean diameter of the filler particles and the mean distances between them in composite materials based on PVC plastigel and low molecular silicone rubber upon heating to the point of emergence of electric conduction.
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References
A. R. Ubbelohde and F. A. Lewis, Graphite and its Crystal Compounds (Clarendon, Oxford, 1960; Mir, Moscow, 1965).
D. D. L. Chung, J. Mater. Sci. 39, 2645 (2004).
M. S. Dresselhaus and G. Dresselhaus, Adv. Phys. 51, 1 (2002).
Yu. E. Lozovik and A. M. Popov, Phys. Usp. 40, 717 (1997).
K. S. Novoselov, A. K. Geim, S. V. Morozov, et al., Science 306, 666 (2004).
S. Stankovich, D. A. Dikin, G. H. B. Dommett, et al., Nature 442, 282 (2006).
I. G. Chernysh, I. I. Karpov, G. P. Prikhod’ko, and V. M. Shai, Physicochemical Properties of Graphite and Its Compounds (Naukova Dumka, Kiev, 1990) [in Russian].
V. V. Avdeev, Extended Abstract of Doctoral Dissertation in Chemistry (Mosc. State Univ., Moscow, 1996).
V. N. Gorshenev and L. D. Kvacheva, in Proceedings of the 4th International Conference on Carbon: Fundamental Problems of Science, Materials, Technology (Moscow State University, Moscow, 2005), p. 87.
S. V. Puchkov, E. V. Puzyreva, G. V. Komarova, and S. D. Fedeseev, Khim. Tverd. Topl., No. 5, 106 (1985).
I. M. Yurkovskii, T. Yu. Smirnova, and L. S. Malei, Khim. Tverd. Topl., No. 1, 127 (1986).
I. M. Yurkovskii, L. S. Malei, T. K. Kuchinskaya, and V. A. Sichevaya, Khim. Tverd. Topl., No. 6, 141 (1985).
G. I. Titelman, V. N. Gelman, Y. V. Isaev, and Y. N. Novikov, Mat. Sci. Forum 91–93, 213 (1992).
V. N. Gorshenev, V. G. Vasil’ev, A. L. Kovarskii, and L. N. Nikitin, Russ. J. Appl. Chem. 82, 1074 (2009).
V. N. Gorshenev and V. L. Demin, Naukoemk. Tekhnol. 8(12), 80 (2007).
Yu. L. Shishkin, Khim. Tekhnol. Topl. Masel, No. 4, 48 (2006).
Yu. L. Shishkin, Thermochim. Acta 440, 156 (2006).
V. N. Gorshenev and A. N. Shchegolikhin, Russ. J. Phys. Chem. B 2, 123 (2008).
V. N. Gorshenev, V. V. Kasparov, and V. V. Kolesov, in Proceedigns of the 11th International Scientific-Technical Conference on Cybernetics and High Technologies of 21st Century (SAKVOOEE, Voronezh, 2010), Vol. 1, p. 335.
A. S. Fialkov and L. S. Malei, in Electrical Carbon and Metal-Ceramic Devices for Electrical Engineering, Collected vol. (Energoatomizdat, Moscow, 1985), p. 65 [in Russian].
W. Rudorff and U. Hofmann, Z. Anorg. Allg. Chem. 238, 1 (1938).
N. Daumas and A. Herold, C.R. Acad. Sci. Paris C 268, 373 (1969).
G. R. Hennig, Prog. Inorg. Chem. 1, 125 (1959).
M. Inagaki, N. Iwashita, and E. Kouno, Carbon 28, 49 (1990).
J. E. Fischer, A. Metrot, P. J. Flanders, et al., Phys. Rev. B 23, 5576 (1981).
M. J. Bottomley, G. S. Parry, A. R. Ubbelohde, and D. A. Young, J. Chem. Soc. (London), No. 12, 5674 (1963).
A. Metrot and J. E. Fischer, Synth. Met. 3(3–4), 201 (1981).
V. V. Avdeev, L. A. Monyakina, I. V. Nikol’skaya, et al., Carbon 39, 819 (1992).
V. N. Gorshenev, Naukoemk. Tekhnol. 10(3), 16 (2009).
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Original Russian Text © V.N. Gorshenev, 2011, published in Khimicheskaya Fizika, 2011, Vol. 30, No. 9, pp. 27–34.
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Gorshenev, V.N. Microwave-assisted and thermal stepwise expansion of oxidized graphites. Russ. J. Phys. Chem. B 5, 780–786 (2011). https://doi.org/10.1134/S1990793111090041
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DOI: https://doi.org/10.1134/S1990793111090041