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Pseudomatrix synthesis of polymer-metal nanocomposite sols: Interaction of macromolecules with metal nanoparticles

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Abstract

The experimental and theoretical data on the effect of macromolecules on the formation of a metal phase during reduction of metal ions in a polymer solution and on the aggregative stability of sols with a narrow size distribution of metal nanoparticles and their small average size are summarized and analyzed. It has been shown that owing to the cooperativity, reversibility, and selectivity of noncovalent interactions of sufficiently long macromolecules with nanoparticles, the dispersion phase of such sols may be regarded as a macromolecule-nanoparticle complex, which forms once a certain size of the particles is achieved and in which the growth of particles ceases. The process of sol synthesis may be regarded as pseudomatrix. The theoretical model developed for the pseudomatrix process of metal phase formation in polymer solutions, which adequately describes the experimental data, makes it possible to control the synthesis conditions of sols of polymer-metal nanocomposites with preset dimensional characteristics of nanoparticles and to govern the aggregative stability of sols.

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References

  1. H. Hirai and N. Toshima, in Polymeric Materials Encyclopedia (CRC, New York, 1996), Vol. 2, p. 1310.

    Google Scholar 

  2. H. Hirai and N. Toshima, in Tailored Metal Catalysts, Ed. by Y. Iwasawa (D. Reidel, Tokyo, 1986), p. 87.

    Google Scholar 

  3. H. Hirai and N. Yakura, Polym. Adv. Technol., No. 12, 724 (2001).

  4. H. Hirai, N. Yakura, Y. Seta, and S. Hodoshima, React. Funct. Polym. 37, 121 (1998).

    Article  CAS  Google Scholar 

  5. Chemical Encyclopedia, Ed. by I. L. Knunyants (Sovetskaya Entsiklopediya, Moscow, 1990) [in Russian].

    Google Scholar 

  6. O. E. Litmanovich and I. M. Papisov, Polymer Science, Ser. A 41, 1169 (1999) [Vysokomol. Soedin., Ser. A 41, 1824 (1999)].

    Google Scholar 

  7. O. E. Litmanovich, A. A. Litmanovich, and I. M. Papisov, Polymer Science, Ser. A 49, 450 (2007) [Vysokomol. Soedin., Ser. A 49, 684 (2007)].

    Article  Google Scholar 

  8. O. E. Litmanovich, G. V. Marmuzov, A. A. Litmanovich, and I. M. Papisov, Polymer Science, Ser. A 46, 841 (2004) [Vysokomol. Soedin., Ser. A 46, 1374 (2004)].

    Google Scholar 

  9. H. Hirai, H. Wakabayashi, and M. Komiyama, Makromol. Chem., Rapid Commun. 5, 381 (1984).

    Article  CAS  Google Scholar 

  10. O. E. Litmanovich and A. A. Litmanovich, Polymer Science, Ser. A 49, 442 (2007) [Vysokomol. Soedin., Ser. A 49, 674 (2007)].

    Article  Google Scholar 

  11. O. E. Litmanovich, A. G. Bogdanov, A. A. Litmanovich, and I. M. Papisov, Polymer Science, Ser. B 39, 403 (1997) [Vysokomol. Soedin., Ser. B 39, 1875 (1997)].

    Google Scholar 

  12. O. E. Litmanovich, A. A. Litmanovich, and I. M. Papisov, Polymer Science, Ser. A 39, 1028 (1997) [Vysokomol. Soedin., Ser. A 39, 1506 (1997)].

    Google Scholar 

  13. O. E. Litmanovich, G. V. Marmuzov, E. A. Eliseeva, et al., Polymer Science, Ser. A 44, 609 (2002) [Vysokomol. Soedin., Ser. A 44, 980 (2002)].

    Google Scholar 

  14. A. A. Chernov, in Modern Crystallography, Ed. by B. K. Vainshtein, A. A. Chernov, and L. A. Shuvalov (Nauka, Moscow, 1980), Vol. 3, p. 7.

    Google Scholar 

  15. B. B. Damaskin and O. A. Petrii, An Introduction to Electrochemical Kinetics (Vysshaya Shkola, Moscow, 1983) [in Russian].

    Google Scholar 

  16. A. N. Frumkin, Zero-Charge Potentials (Nauka, Moscow, 1982) [in Russian].

    Google Scholar 

  17. L. I. Antropov, Theoretical Electrochemistry (Nauka, Moscow, 1984) [in Russian].

    Google Scholar 

  18. B. B. Damaskin and O. A. Petrii, Electrochemistry (Vysshaya Shkola, Moscow, 1987) [in Russian].

    Google Scholar 

  19. A. D. Pomogailo, A. S. Rozenberg, and I. E. Uflyand, Metal Nanoparticles in Polymers (Khimiya, Moscow, 2000) [in Russian].

    Google Scholar 

  20. V. V. Sviridov, T. N. Vorob’eva, T. V. Gaevskaya, and L. I. Stepanova, Chemical Precipitation of Metals in Aqueous Solutions (Universitetskoe, Minsk, 1987) [in Russian].

    Google Scholar 

  21. K. Inoue, A. Kitakhara, S. Koseki, et al., in Interface Chamistry, Ed. by K. Tamaru (Iwanami Shoten, Tokyo, 1980; Mir, Moscow, 1983).

    Google Scholar 

  22. Yu. I. Petrov, Clusters and Small Particles (Nauka, Moscow, 1986) [in Russian].

    Google Scholar 

  23. A. Henglein, Elektrochem. Met. 93, 1914 (1983).

    Google Scholar 

  24. O. E. Litmanovich, A. G. Bogdanov, and I. M. Papisov, Polymer Science, Ser. B 43, 26 (2001) [Vysokomol. Soedin., Ser. B 43, 135 (2001)].

    Google Scholar 

  25. J. Dzubiella, A. G. Moreira, and P. A. Pincus, Macromolecules 36, 1741 (2003).

    Article  CAS  Google Scholar 

  26. A. A. Litmanovich and I. M. Papisov, Polymer Science, Ser. B 39, 41 (1997) [Vysokomol. Soedin., Ser. B 39, 323 (1997)].

    Google Scholar 

  27. I. M. Papisov, Polymer Science, Ser. B 39, 122 (1997) [Vysokomol. Soedin., Ser. B 39, 562 (1997)].

    Google Scholar 

  28. A. T. Clark, I. D. Robb, and R. Smith, J. Chem. Soc., Faraday Trans. 72, 1489 (1976).

    Article  CAS  Google Scholar 

  29. A. D. Barrios and G. J. Howard, Makromol. Chem. 182, 1081 (1981).

    Article  Google Scholar 

  30. M. Kawaguchi and A. Takahashi, J. Polym. Sci., Part B: Polym. Phys. 18, 2069 (1980).

    CAS  Google Scholar 

  31. L. N. Ermakova, Yu. G. Frolov, V. A. Kasaikin, et al., Vysokomol. Soedin., Ser. A 23, 2328 (1981).

    CAS  Google Scholar 

  32. R. R. Netz and J.-F. Joanny, Macromolecules 32, 9026 (1999).

    Article  CAS  Google Scholar 

  33. O. A. Kharenko, A. V. Kharenko, R. I. Kalyuzhnaya, et al., Vysokomol. Soedin., Ser. A 21, 2719 (1979).

    CAS  Google Scholar 

  34. V. A. Izumrudov, O. A. Kharenko, A. V. Kharenko, et al., Vysokomol. Soedin., Ser. A 22, 692 (1980).

    CAS  Google Scholar 

  35. V. A. Efremov, A. R. Khokhlov, and Yu. V. Shikina, Polymer Science 34, 484 (1992) [Vysokomol. Soedin., Ser. A 34, 37 (1992)].

    Google Scholar 

  36. O. E. Litmanovich, A. G. Bogdanov, and I. M. Papisov, Polymer Science, Ser. B 43, 312 (2001) [Vysokomol. Soedin., Ser. B 43, 2020 (2001)].

    Google Scholar 

  37. O. E. Litmanovich, E. A. Eliseeva, A. G. Bogdanov, and I. M. Papisov, Polymer Science, Ser. B 45, 62 (2003) [Vysokomol. Soedin., Ser. B 45, 507 (2003)].

    Google Scholar 

  38. Yu. E. Kirsh, Poly(N-vinylpyrrolidone) and Other Poly(N-vinylamides) (Nauka, Moscow, 1998) [in Russian].

    Google Scholar 

  39. O. E. Litmanovich, A. A. Litmanovich, and I. M. Papisov, Polymer Science, Ser. A 42, 442 (2000) [Vysokomol. Soedin., Ser. A 42, 670 (2000)].

    Google Scholar 

  40. I. M. Papisov, K. I. Bolyachevskaya, Yu. S. Yablokov, et al., Macromol. Symp. 106, 287 (1996).

    CAS  Google Scholar 

  41. I. M. Papisov, in Polymeric Materials Encyclopedia (CRC, New York, 1996), Vol. 6, p. 4038.

    Google Scholar 

  42. I. M. Papisov and A. A. Litmanovich, Adv. Polym. Sci. 90, 140 (1989).

    Google Scholar 

  43. V. A. Kabanov and I. M. Papisov, Vysokomol. Soedin., Ser. A 21, 243 (1979).

    CAS  Google Scholar 

  44. I. M. Papisov and A. A. Litmanovich, Vysokomol. Soedin., Ser. A 19, 716 (1977).

    CAS  Google Scholar 

  45. I. M. Papisov and A. A. Litmanovich, in Polymeric Materials Encyclopedia (CRC, New York, 1996), Vol. 6, p. 4457.

    Google Scholar 

  46. I. M. Papisov and A. A. Litmanovich, Colloids Surf., A 151, 399 (1999).

    Article  CAS  Google Scholar 

  47. O. E. Litmanovich, A. G. Bogdanov, A. A. Litmanovich, and I. M. Papisov, Polymer Science, Ser. B 40, 15 (1998) [Vysokomol. Soedin., Ser. B 40, 100 (1998)].

    Google Scholar 

  48. O. E. Litmanovich, G. V. Marmuzov, A. A. Litmanovich, and I. M. Papisov, Polymer Science, Ser. A 45, 906 (2003) [Vysokomol. Soedin., Ser. A 45, 1533 (2003)].

    Google Scholar 

  49. O. E. Litmanovich, E. A. Eliseeva, A. A. Litmanovich, and I. M. Papisov, Polymer Science, Ser. A 43, 813 (2001) [Vysokomol. Soedin., Ser. A 43, 1315 (2001)].

    Google Scholar 

  50. K. Hayakawa and J. Kwak, J. Phys. Chem. 87, 506 (1983).

    Article  CAS  Google Scholar 

  51. K. Hayakawa and J. Kwak, J. Phys. Chem. 86, 3866 (1982).

    Article  CAS  Google Scholar 

  52. K. Hayakawa, T. Fukutome, and I. Satake, Langmuir 6, 1495 (1990).

    Article  CAS  Google Scholar 

  53. P. L. Dubin, M. E. Curran, and J. Him, Langmuir 6, 707 (1990).

    Article  CAS  Google Scholar 

  54. I. Satake, T. Takahashi, K. Hayakawa, et al., Bull. Chem. Soc. Jpn. 63, 926 (1990).

    Article  CAS  Google Scholar 

  55. J. J. Kiefer, P. Somasundaran, and K. P. Ananthapadmanabhan, Langmuir 9, 1187 (1993).

    Article  CAS  Google Scholar 

  56. X. H. Feng, P. L. Dubin, H. W. Zhang, et al., Macromolecules 34, 6373 (2001).

    Article  CAS  Google Scholar 

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  1. Moscow State Automobile and Road Technical University, Leningradskii pr. 64, Moscow, 125829, Russia

    O. E. Litmanovich

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Original Russian Text © O.E. Litmanovich, 2008, published in Vysokomolekulyarnye Soedineniya, Ser. C, 2008, Vol. 50, No. 7, pp. 1370–1396.

This work was supported by the Russian Foundation for Basic Research (project no. 05-03-32025) and the agency target program “Development of the Scientific Potential of Higher Schools” (2006–2008) (project no. RNP.2.1.1.4914).

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Litmanovich, O.E. Pseudomatrix synthesis of polymer-metal nanocomposite sols: Interaction of macromolecules with metal nanoparticles. Polym. Sci. Ser. C 50, 63–84 (2008). https://doi.org/10.1134/S1811238208010049

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