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Green Synthesis Method of Poly[(2,5-diyl pyrrole)(4-hydroxy-3-methoxy benzylidene)] Semiconductor Polymer Using an Ecologic Catalyst

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Abstract

A new synthesis of poly[(2,5-diyl pyrrole)(4-hydroxy-3-methoxy benzylidene)] copolymer was achieved via the polycondensation of vanillin and pyrrole in bulk and in solution using CH2Cl2 as solvent with acid exchanged montmorillonite clay called Maghnite-H+, a green catalyst initiator, non-toxic and recoverable by simple filtration. The effects of several parameters, such as the amount of catalyst, time and temperature of the polymerization and molar ratio of monomers on the polymers yield were studied. The conjugated polymer was characterized by means of 1H NMR, Fourier transform infrared spectroscopy and UV–Visible spectroscopy, as well as X-ray diffraction. The thermal properties of the prepared polymers were studied by thermogravimetric analysis. Poly[(2,5-diyl pyrrole)(4-hydroxy-3-methoxy benzylidene)] was found to be a semiconductive polymer.

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Authors and Affiliations

  1. Laboratoire de Chimie des Polymères, Faculté des Sciences Exactes et Appliquées, Université Oran1, BP 1524, 31000, El-Menouer Oran, Algérie

    Anas Abderrahmane Lahouel, Nacera Miloudi & Nabahat Sahli

  2. Laboratoire d’Application des Electrolytes et des Polyélectrolytes Organiques (LAEPO), Département de Chimie, Université de Tlemcen, BP 119, 13000, Tlemcen, Algérie

    Kouider Medjahed

  3. Laboratoire de Recherche sur les Macromolécules, Département de Physique, Université de Tlemcen, BP 119, 13000, Tlemcen, Algérie

    Abdelkader Berrayah

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  1. Anas Abderrahmane Lahouel
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  2. Nacera Miloudi
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Anas Abderrahmane Lahouel, Miloudi, N., Medjahed, K. et al. Green Synthesis Method of Poly[(2,5-diyl pyrrole)(4-hydroxy-3-methoxy benzylidene)] Semiconductor Polymer Using an Ecologic Catalyst. Polym. Sci. Ser. B 64, 715–724 (2022). https://doi.org/10.1134/S1560090422700348

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