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Photoinduced Processes in System Ferrocene + Cyanate Ester

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Abstract

The kinetics of processes related to the dissociation of ferrocene in bisphenol А dicyanate oligomer under UV light is studied. Using the kinetic data rate constants are calculated and assumption regarding the mechanism of photochemical reactions occurring in the system is made. The photodissociation of ferrocene under medium-wave UV irradiation becomes possible due to the presence of cyanate ester iminocarbamate derivatives in the oligomer mixture.

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Funding

This work was performed within the framework of complex scientific direction 10 “Energy-effective, resource-saving, and additive technologies for producing parts, semi-finished products, and structures” (Strategic directions for the development of materials and their processing technologies for the period up to 2030) [25].

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Authors and Affiliations

  1. All-Russian Scientific Research Institute of Aviation Materials, National Research Center Kurchatov Institute, 105005, Moscow, Russia

    D. A. Gurov & G. F. Novikov

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    E. S. Sorin

Authors
  1. D. A. Gurov
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  2. E. S. Sorin
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  3. G. F. Novikov
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Corresponding author

Correspondence to D. A. Gurov.

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The authors declare that they have no conflicts of interest.

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Translated by T. Soboleva

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Gurov, D.A., Sorin, E.S. & Novikov, G.F. Photoinduced Processes in System Ferrocene + Cyanate Ester. Polym. Sci. Ser. B 64, 567–572 (2022). https://doi.org/10.1134/S1560090422700312

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  • DOI: https://doi.org/10.1134/S1560090422700312

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