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Obtainment and Comparative Study of Electrochemical Behavior of Composite Electrodes Based on Polyaniline and Its N-Substituted Derivatives

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Abstract

Hybrid polymer nanomaterials based on N-substituted polyanilines and graphene oxide are synthesized for the first time via the in situ oxidative polymerization of 3,6-dianiline-2,5-dichloro-1,4-benzoquinone and 3,6-phenylenediamine-2,5-dichloro-1,4-benzoquinone in the presence of graphene oxide. The morphology and electrochemical properties of composite electrodes made of graphite foil support covered with polyaniline (or nanocomposites based on its derivatives containing the polyaniline chain with electroactive N-substituents and graphene oxide) coating are studied. It is shown that the electroconductive nanocomposite material characterized by the electrochemical capacitance above 1000 F/g and the stability of capacitive characteristics under prolonged charge/discharge cycles in a proton (1М H2SO4) electrolyte is formed on the graphite foil support.

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References

  1. H. Peng, G. F. Ma, W. M. Ying, A. D. Wang, H. H. Huang, and Z. Q. Lei, J. Power Sources 211, 40 (2012).

    Article  CAS  Google Scholar 

  2. W. Wang, F. Zhu, Y. Dai, H. Zhang, and Y. Chen, Russ. J. Electrochem. 53, 147 (2017).

    Article  CAS  Google Scholar 

  3. O. Ya. Mezhuev, Yu. V. Korshak, and M. I. Shtil’man, Russ. Chem. Rev. 86, 1271 (2017).

    Article  CAS  Google Scholar 

  4. Y. M. Shulga, S. A. Baskakov, V. V. Abalyaeva, O. N. Efimov, N. Y. Shulga, A. Michtchenko, L. LartundoRojas, L. A. Moreno-R, J. G. Cabañas-Moreno, and V. N. Vasilets, J. Power Sources 224, 195 (2013).

    Article  CAS  Google Scholar 

  5. V. V. Abalyaeva, S. A. Baskakov, and N. N. Dremova, Russ. J. Electrochem. 51, 916 (2015).

    Article  CAS  Google Scholar 

  6. T. Lee, T. Yun, B. Park, B. Sharma, H. Song, and B. Kim, J. Mater. Chem. 22, 21092 (2012).

    Article  CAS  Google Scholar 

  7. E. M. Geniès, M. Lapkowski, and J. F. Penneau, J. Electroanalyt. Chem. Interfacial Electrochem. 249, 97 (1988).

    Article  Google Scholar 

  8. Y. Kieffel, J. Pierre Travers, A. Ermolieff, and D. Rouchon, J. Appl. Polym. Sci. 86, 395 (2002).

    Article  CAS  Google Scholar 

  9. V. V. Abalyaeva, L. I. Tkachenko, G. V. Nikolaeva, A. V. Orlov, S. G. Kiseleva, O. N. Efimov, and G. P. Karpacheva, Polym. Sci., Ser. B 59, 459 (2017).

    Article  CAS  Google Scholar 

  10. S. G. Kiseleva, A. V. Orlov, and G. P. Karpacheva, Polym. Sci., Ser. B 60, (2018). (in press).

    Google Scholar 

  11. S. G. Kiseleva, A. V. Orlov, T. A. Borukaev, G. N. Bondarenko, and G. P. Karpacheva, in Proceedings of XIII International Research and Practice Conference “New Polymer Composite Materials”, Nalchik, Russia, 2017 (Print Tsentr, Nalchik, 2017), p. 110.

    Google Scholar 

  12. Y. G. Wang, H.-Q. Li, and Y.-Y. Xia, Adv. Mater. 18, 2619 (2006).

    Article  CAS  Google Scholar 

  13. V. V. Abalyaeva, S. A. Baskakov, and N. N. Dremova, Russ. J. Electrochem. 51, 976 (2015).

    Article  CAS  Google Scholar 

  14. R. V. Salvatierra, G. Zitzer, S.-A. Savu, A. P. Alves, A. J. G. Zarbin, T. Chasse, M. B. Casu, and M. L. M. Rocco, Synth. Met. 203, 16 (2015).

    Article  CAS  Google Scholar 

  15. A. Falcou, A. Longeau, D. Marcsacq, P. Hourquebie, and A. Duchene, Synth. Met. 101, 647 (1999).

    Article  CAS  Google Scholar 

  16. I. Šedenková, E. N. Kohyushenko, J. Stejskal, M. Trchová, and J. Prokeš, Synth. Met. 161, 1353 (2011).

    Article  CAS  Google Scholar 

  17. Y. S. Negi and P. V. Adhyapak, J. Macromol. Sci., Part C: Polym. Rev. 42, 35 (2002).

    Article  Google Scholar 

  18. M. Trchova and J. Stejskal, Pure Appl. Chem. 83, 1803 (2011).

    Article  CAS  Google Scholar 

  19. M. S. Refat, O. B. Ibrahim, H. Al-Didamony, K. M. A. El-Noir, and L. El-Zayat, J. Saudi Chem. Soc. 16, 227 (2012).

    Article  CAS  Google Scholar 

  20. M. S. Refat, L. El-Zayat, and O. Z. Yesilel, Polyhedron 27, 475 (2008).

    Article  CAS  Google Scholar 

  21. X. Zhang, R. Chan-Yu-King, A. Jose, and S. K. Manohar, Synth. Met. 145, 23 (2004).

    Article  CAS  Google Scholar 

  22. J. Kan and Sh. Zhang, Synth. Met. 145, 37 (2004).

    Article  CAS  Google Scholar 

  23. N. E. Sorokina, I. V. Nikol’skaya, S. G. Ionov, and V. V. Avdeev, Russ. Chem. Bull. 54, 1749 (2005).

    Article  CAS  Google Scholar 

  24. N. S. Grigoryan, A. A. Gubanov, T. A. Vagramyan, and Yu. V. Korshak, Russ. J. Appl. Chem. 88, 1150 (2015).

    Article  CAS  Google Scholar 

  25. M. Kim, Ch. Lee, and J. Jang, Adv. Funct. Mater. 24, 2489 (2014).

    Article  CAS  Google Scholar 

  26. V. V. Abalyaeva, S. A. Baskakov, and N. N. Dremova, Russ. J. Electrochem. 51, 916 (2015).

    Article  CAS  Google Scholar 

  27. L. Al-Mashat, K. Shin, K. Kalantar-zadeh, J. D. Plessis, H. R. W. Kojima, R. B. Kaner, D. Li, X. Gou, S. J. Ippolito, and W. W. Wodarski, J. Phys. Chem. C 114, 16168 (2010).

    Article  CAS  Google Scholar 

  28. Y.-Z. Hong, H.-Ch. Tsai, Y.-H. Wang, J. Aumanen, P. Myllyperkiö, A. Johansson, L.-Y. Chang, Ch.-H. Chen, M. Pettersson, and W.-Y. Woon, Carbon 129, 396 (2018).

    Article  CAS  Google Scholar 

  29. C. Vix-Guterl, E. Frackowiak, K. Jurewicz, M. Friebe, J. Parmentier, and F. Béguin, Carbon 43, 1293 (2005).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Abalyaeva, G. V. Nikolaeva, E. N. Kabachkov & O. N. Efimov

  2. Topchiev Intstitute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    S. G. Kiseleva, A. V. Orlov & G. P. Karpacheva

  3. Chernogolovka Scientific Center, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    E. N. Kabachkov

Authors
  1. V. V. Abalyaeva
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  2. G. V. Nikolaeva
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  3. E. N. Kabachkov
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  4. S. G. Kiseleva
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  5. A. V. Orlov
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  6. O. N. Efimov
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  7. G. P. Karpacheva
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Corresponding author

Correspondence to S. G. Kiseleva.

Additional information

Original Russian Text © V.V. Abalyaeva, G.V. Nikolaeva, E.N. Kabachkov, S.G. Kiseleva, A.V. Orlov, O.N. Efimov, G.P. Karpacheva, 2018, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2018, Vol. 60, No. 6, pp. 505–514.

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Abalyaeva, V.V., Nikolaeva, G.V., Kabachkov, E.N. et al. Obtainment and Comparative Study of Electrochemical Behavior of Composite Electrodes Based on Polyaniline and Its N-Substituted Derivatives. Polym. Sci. Ser. B 60, 780–788 (2018). https://doi.org/10.1134/S1560090418060015

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  • DOI: https://doi.org/10.1134/S1560090418060015

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