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Thermooxidative stabilization of acrylonitrile terpolymers obtained under reversible chain-transfer conditions: Effects of synthesis temperature and initiation method

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Abstract

The terpolymerization of acrylonitrile, methyl acrylate, and itaconic acid mediated by a reversible addition-fragmentation chain transfer agent, dibenzyl trithiocarbonate, and initiated by AIBN at 80°C, potassium persulfate at 45–55°C, and radiolysis at 20°C is studied. In all the cases, polymerization proceeds via the pseudoliving mechanism, which is preserved up to ultimately high monomer conversions (80–90%). According to FTIR ATR and NMR spectroscopy, all the synthesized terpolymers are characterized by close monomer compositions and their degree of branching is too low to be detected spectroscopically. However, the thermal behaviors of terpolymers obtained by polymerizations at various temperatures are different, namely, the lower the temperature of terpolymer synthesis, the slower the thermooxidative stabilization processes occurring in it.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    E. V. Chernikova & A. V. Plutalova

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    E. V. Chernikova & S. A. Legkov

  3. Institute of Fine Chemical Technologies, Moscow Technological University, pr. Vernadskogo 86, Moscow, 119571, Russia

    R. V. Toms & N. I. Prokopov

  4. AO State Research Centre of the Russian Federation, Karpov Research Institute of Physical Chemistry, 109 km, Kievskoe sh. 6, Obninsk, Kaluga oblast, 249033, Russia

    V. R. Duflot

  5. National Research Centre Kurchatov Institute, pl. Akademika Kurchatova 1, Moscow, 123182, Russia

    V. I. Gomzyak

Authors
  1. E. V. Chernikova
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  2. R. V. Toms
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  3. N. I. Prokopov
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  4. V. R. Duflot
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  5. A. V. Plutalova
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  6. S. A. Legkov
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  7. V. I. Gomzyak
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Correspondence to E. V. Chernikova.

Additional information

Original Russian Text © E.V. Chernikova, R.V. Toms, N.I. Prokopov, V.R. Duflot, A.V. Plutalova, S.A. Legkov, V.I. Gomzyak, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2017, Vol. 59, No. 1, pp. 12–27.

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Chernikova, E.V., Toms, R.V., Prokopov, N.I. et al. Thermooxidative stabilization of acrylonitrile terpolymers obtained under reversible chain-transfer conditions: Effects of synthesis temperature and initiation method. Polym. Sci. Ser. B 59, 28–42 (2017). https://doi.org/10.1134/S156009041701002X

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  • DOI: https://doi.org/10.1134/S156009041701002X

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