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Chemical polymerization of aniline in the presence of mixtures of polymeric sulfonic acids

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Abstract

The template polymerization of aniline in the presence of polymeric sulfonic acids of various structures and their mixtures is studied. In the latter case, the dominant effect of a polyacid on the kinetics of aniline polymerization and the electronic structure of the resulting polyaniline complex is observed. As shown by viscometry measurements and IR studies, the intermolecular interaction between polyacids in their mixtures that leads to a change in the conformation of a flexible-chain polyacid is responsible for the dominant effect of a rigid-chain polyacid. The spectral and electrical properties of polyaniline-based interpolymer complexes are examined.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    O. D. Omel’chenko, O. L. Gribkova, A. A. Nekrasov, V. F. Ivanov & A. V. Vannikov

  2. Moscow University of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571, Russia

    V. V. Kravchenko & V. A. Tverskoi

Authors
  1. O. D. Omel’chenko
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  2. O. L. Gribkova
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  3. A. A. Nekrasov
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  4. V. F. Ivanov
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  5. V. V. Kravchenko
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  6. A. V. Vannikov
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  7. V. A. Tverskoi
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Corresponding author

Correspondence to O. L. Gribkova.

Additional information

Original Russian Text © O.D. Omel’chenko, O.L. Gribkova, A.A. Nekrasov, V.F. Ivanov, V.V. Kravchenko, A.V. Vannikov, V.A. Tverskoi, 2013, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2013, Vol. 55, No. 4, pp. 454–462.

This work was supported in part by the Russian Foundation for Basic Research, project no. 12-03-90435-Ukr_a.

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Omel’chenko, O.D., Gribkova, O.L., Nekrasov, A.A. et al. Chemical polymerization of aniline in the presence of mixtures of polymeric sulfonic acids. Polym. Sci. Ser. B 55, 187–194 (2013). https://doi.org/10.1134/S1560090413040064

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  • DOI: https://doi.org/10.1134/S1560090413040064

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