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Interpolyelectrolyte Complexes of Polyaniline and Sulfonated Poly(phenylene oxide)

  • ON THE 80th ANNIVERSARY OF THE BIRTH OF A. B. ZEZIN
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Abstract

The oxidative polymerization of aniline is studied for the first time in the presence of sulfonated poly(2,6-dimethyl-1,4-phenylene oxide). The polymerization leads to the formation of polyaniline-sulfonated poly(2,6-dimethyl-1,4-phenylene oxide) interpolyelectrolyte complexes in which polyaniline is in the protonated form (as emeraldine salt). It is shown that the polyaniline–sulfonated poly(2,6-dimethyl-1,4-phenylene oxide) complexes, depending on their composition, have either only proton conductivity from 0.015 to 0.1 S/cm, or mixed electronic-proton conductivity (10–6 S/cm electronic conductivity and 0.015 S/cm proton conductivity), or only electronic conductivity (up to 10–2 S/cm).

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Funding

This work was carried out within the project Modern Problems of Chemistry and Physical Chemistry of High Molecular Weight Compounds (State Budget, no. AAAA-A16-116031050014-6).

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119992, Moscow, Russia

    A. V. Kubarkov, P. I. Turkina, A. S. Shepeleva, O. A. Pyshkina, Yu. A. Zakharova & V. G. Sergeyev

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  1. A. V. Kubarkov
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  2. P. I. Turkina
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  3. A. S. Shepeleva
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  4. O. A. Pyshkina
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  5. Yu. A. Zakharova
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  6. V. G. Sergeyev
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Corresponding author

Correspondence to O. A. Pyshkina.

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Kubarkov, A.V., Turkina, P.I., Shepeleva, A.S. et al. Interpolyelectrolyte Complexes of Polyaniline and Sulfonated Poly(phenylene oxide). Polym. Sci. Ser. B 61, 691–697 (2019). https://doi.org/10.1134/S1560090419060083

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  • DOI: https://doi.org/10.1134/S1560090419060083

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