Abstract
AB diblock copolymers of poly(2-(dimethylamino)ethyl metharylate-block-potassiurn acrylate) were prepared via reversible addition-fragmentation chain transfer (RAFT) polymerization. The structure of the block polymer was determined by the nuclear magnetic resonance (NMR) spectroscopy and the gel permeation chromatography. Moreover, it has also been shown that the diblock copolymers exhibit aggregate as function of the pH according to the result of 1H-NMR spectroscopy, FT-IR absorption spectra, UV-vis transmittance spectroscopy, transmission electron microscopy and ultrasonic particle size analyzer. The result was attributed that such AB diblock copolymers were tailored to undergo pH-induced self-assembly. Furthermore, the aggregate can be as template of metal nanoparticles preparation, and the sizes of the aggregate, in turn, strongly control nanoparticle sizes.
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References
F. Remacle and R. D. Levine, Chem. Phys. Chem. 2, 20 (2001).
A. J. Convertine, N. Ayres, C.W. Scales, A. B. Lowe, and C.L. McCormick, Biomacromolecules 5, 1177 (2004).
N. Murthy, J. Campbell, N. Fausto, A.S. Hoffman, and P.S. Stayton, Bioconjugate Chem. 14, 412 (2003).
K. Prochazka, T. J. Martin, P. Munk, and S. E. Webber, Macromolecules 20, 6518 (1996).
S. B. Fan and T. Kyu, Macromolecules 33, 9568 (2000).
T. B. Hoang, K. Toshio, K. Masanao, A. Miyazawa, T. K. Ishihara, H. D. Hagihara, et al., Macromolecules 39, 171 (2006).
H. Watanabe, T. Sato, and K. Osaki, Macromolecules 29, 104 (1996).
H. Watanabe, T. Sato, and K. Osaki, Macromolecules 29, 113 (1996).
S. Brahim, D. Narinesingh, and A. Guiseppi-Elie, Biomacromolecules 4, 1224 (2003).
A. B. Lowe, N. C. Billingham, and S. P. Armes, Macromolecules 31, 5991 (1998).
M. S. Kyriacou, S.C. Hadjiyannakou, M. Vamvakaki, and C.S. Patrickios, Macromolecules 37, 7181 (2004).
J.-F.ois Gohy, S. Creutz, M. Garcia, B. Mahltig, M. Stamm, and R. Je’rôme, Macromolecules 33, 6378 (2000).
Q. Zhao and P. H. Ni, Polymer 46, 3141 (2005).
S. L. Sin, L. H. Gan, X. Hu, K. C. Tam, and Y. Y. Gan, Macromolecules 38, 3943 (2005).
Yue Jianxin, Wen Guohua, Wang Lili, and Sun Guoqiang, Chinese Journal of Colloid & polymer 22, 17 (2004).
G. Moad, E. Rizzardo, and S.H. Thang, Polymer 49, 1079 (2008).
Y.Y. Sun, Y.Q. Liu, G.Z. Zhao, X. Zhou, J.G. Gao, and Q.J. Zhang, Journal of Materials Science 43, 4625 (2008).
V. Bütün, C. E. Bennett, M. Vamvakaki, A. B. Lowe, N. C. Billingham, and S. P. Armes, J. Mater. Chem. 7, 1693 (1997).
M. L. Becker, E. E. Remsen, and K. L. Wooley, Journal of Polymer Science Part A: Polymer Chemistry 39, 4152 (2001).
K. Hanabusa, X. J. Ye, A. Kurose, H. Shirai, T. Hayakawa, and N. Hojo, Journal of Polymer Science Part A: Polymer Chemistry 27, 4191 (1989).
Y. Y. Sun, D. Wang, G. J. Gao, Z. Zheng, and Q. J. Zhang, Journal of Applied Polymer Science 103, 3701 (2007).
Y. Y. Sun, Y. Q. Liu, G. Z. Zhao, and Q. J. Zhang, Journal of Applied Polymer Science 107, 9 (2008).
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Liu, Y., Jing, F., Sun, Y. et al. Simple synthesis of zwitterionic diblock copolymers for the application on metal nanoparticles preparation. Polym. Sci. Ser. B 52, 492–497 (2010). https://doi.org/10.1134/S1560090410070158
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DOI: https://doi.org/10.1134/S1560090410070158