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Free-radical polymerization of methyl methacrylate in the presence of a ferrocenyl-containing iron(II) clathrochelate complex and initiators of various natures

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Abstract

Benzoyl peroxide-, lauryl peroxide-, and AIBN-initiated free-radical polymerization of methyl methacrylate has been studied in bulk and solution in the presence of macrobicyclic iron(II) bis(ferrocenyl borate) tris(nioximate). It has been found that the ferrocenyl-containing iron(II) clathrochelate forms efficient initiating systems with peroxides, whereas, in the case of AIBN, its presence has no effect on the kinetic parameters of the process and the properties of the resulting polymer. The use of clathrochelate complex-peroxide initiator systems accelerates the polymerization of methyl methacrylate and decreases the molecular mass of the polymer. The kinetic parameters of the process have been determined.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    R. M. Islamova, G. R. Sadykova, I. A. Ionova & Yu. B. Monakov

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    Ya. Z. Voloshin, Yu. N. Bubnov & I. S. Makarov

Authors
  1. R. M. Islamova
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  2. G. R. Sadykova
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  3. I. A. Ionova
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  4. Ya. Z. Voloshin
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  5. Yu. N. Bubnov
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  6. I. S. Makarov
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  7. Yu. B. Monakov
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Corresponding author

Correspondence to Yu. B. Monakov.

Additional information

Original Russian Text © R.M. Islamova, G.R. Sadykova, I.A. Ionova, Ya.Z. Voloshin, Yu.N. Bubnov, I.S. Makarov, Yu.B. Monakov, 2009, published in Vysokomolekulyarnye Soedineniya, Ser. B, 2009, Vol. 51, No. 7, pp. 1204–1210.

This work was supported by the Russian Foundation for Basic Research (project nos. 06-03-32626-a, 07-03-00281, and 08-03-90107-mol-a) and the program Leading Scientific Schools (project nos. NSh-2186.2008.3 and NSh-3834.2008.3).

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Islamova, R.M., Sadykova, G.R., Ionova, I.A. et al. Free-radical polymerization of methyl methacrylate in the presence of a ferrocenyl-containing iron(II) clathrochelate complex and initiators of various natures. Polym. Sci. Ser. B 51, 219–225 (2009). https://doi.org/10.1134/S1560090409070033

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  • DOI: https://doi.org/10.1134/S1560090409070033

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