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Infrared Spectroscopy of Composite Materials Based on High-Silica Porous Glasses Activated by Bismuth and Yttrium Ions

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Abstract

Composite materials (CMs) based on matrices of high-silica nanoporous glasses (NPGs) activated by bismuth and yttrium ions are synthesized. The CMs are studied by IR spectroscopy (1000–400 cm–1), depending on the Bi/Y nitrate ratio in the solution (1 : 1 and 10 : 1) and the heat treatment temperature of the CMs (from 470 to 870°C). The method of IR spectroscopy in composites identifies vibrations characteristic of the cubic modification Y2O3 and for the monoclinic modification of bismuth oxide (α–Bi2O3); for vibrations of Bi–O and Bi–O–Bi bonds, as well as Bi3+ cations in [BiO6] and/or [Bio3] structural units; and for vibrations of Bi–O–Si bonds, and for Y–O–Y and Y–O bonds. It is established that an increase in the yttrium content in CMs heat-treated at 470 and 870°C, (all other things being equal) leads to the appearance of additional absorption bands at 564, 556, 432, and 424 cm–1, which may be related to the formation of the cubic phase Y2O3.

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Funding

This work was supported by the RF Ministry of Science and Higher Education as part of the state assignment of the the Institute of Silicate Chemistry, Russian Academy of Sciences (state registration no. AAAA-A19-119022290087-1 and no. 1021050501068-5-1.4.3 (project FFEM-2022-0004)).

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    M. A. Girsova, G. F. Golovina & L. N. Kurilenko

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  1. M. A. Girsova
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  2. G. F. Golovina
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  3. L. N. Kurilenko
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Correspondence to M. A. Girsova.

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Girsova, M.A., Golovina, G.F. & Kurilenko, L.N. Infrared Spectroscopy of Composite Materials Based on High-Silica Porous Glasses Activated by Bismuth and Yttrium Ions. Glass Phys Chem 48, 588–593 (2022). https://doi.org/10.1134/S1087659622600430

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  • DOI: https://doi.org/10.1134/S1087659622600430

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