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Infrared Spectroscopy Study of Composite Materials Based on Nanoporous High-Silica Glasses Activated with Silver and Lanthanum Ions

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Abstract

Composite materials (CMs) activated by silver and lanthanum ions based on high-silica porous glass (PG) matrices have been synthesized. The CMs were studied by IR spectroscopy in the narrow frequency range of 1000–400 cm–1 at room temperature. The bands corresponding to the Ag–O, Ag–O–Ag, O–Ag–O, La–O–H, and La–O bonds vibrations were detected on the infrared transmission spectra of the CMs. In addition, bands corresponding to the presence of Ag2O, La2O3 were found. Accordingly the energy-dispersive X-ray spectroscopy method the lanthanum and silver are evenly distributed throughout the thickness of the samples.

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REFERENCES

  1. Subhan, Md. A., Fahim, A.M.M., Saha, P.C., Rahman, M.M., Begum, K., and Azad, A.K., Structural study, photoluminescence and photocatalytic properties of La2O3–Fe3O4–ZnO, AgO–NiO–ZnO and La2O3–AgO–ZnO nanocomposites, Nano-Struct. Nano-Objects, 2017, vol. 10, pp. 30–41.

    Article  CAS  Google Scholar 

  2. Jadhav, S.B., Malavekar, D.B., Bulakhe, R.N., and Patil, U.M., In I., Lokhande, C.D., and Pawaskar, P.N., Dual-functional electrodeposited vertically grown Ag-La2O3 nanoflakes for non-enzymatic glucose sensing and energy storage application, Surf. Interfaces, 2021, vol. 23, 101018.

    Book  Google Scholar 

  3. Wang, K., Wu, Y., Li, H., Li, M., Guan, F., and Fan, H., A hybrid antioxidizing and antibacterial material based on Ag–La2O3 nanocomposites, J. Inorg. Biochem., 2014, vol. 141, pp. 36–42.

    Article  CAS  Google Scholar 

  4. Fudzi, F.M., Kamari, H.M., Muhammad, F.D., Latif, A.A., and Ismail, Z., Structural and optical properties of zinc borotellurite glass co-doped with lanthanum and silver oxide, J. Mater. Sci. Chem. Eng., 2018, vol. 6, pp. 18–23.

    CAS  Google Scholar 

  5. Kang, J.-G., Kim, Y.-Il., Cho, D.W., and Sohn, Y., Synthesis and physicochemical properties of La(OH)3 and La2O3 nanostructures, Mater. Sci. Semicond. Process., 2015, vol. 40, pp. 737–743.

    Article  CAS  Google Scholar 

  6. Gaddam, A., Fernandes, H.R., Tulyaganov, D.U., and Ferreira, J.M.F., The structural role of lanthanum oxide in silicate glasses, J. Non-Cryst. Solids, 2019, vol. 505, pp. 18–27.

    Article  CAS  Google Scholar 

  7. Antropova, T., Girsova, M., Anfimova, I., Drozdova, I., Polyakova, I., and Vedishcheva, N., Structure and spectral properties of the photochromic quartz-like glasses activated by silver halides, J. Non-Cryst. Solids, 2014, vol. 401, pp. 139–141.

    Article  CAS  Google Scholar 

  8. Antropova, T.V., Girsova, M.A., Anfimova, I.N., Golovina, G.F., Kurilenko, L.N., and Firstov, S.V., Production method of luminescent bismuth-containing quartz-like material based on high-silica porous glass, RF Patent. 2605711, Byull. Izobret., 2016, no. 36.

  9. Guerreiro, H.M., Melnikov, P., Arkhangelsky, I., de Oliveira, L.C.S., Wandekoken, G.A., and do Nascimento, V.A., Thermal decomposition of lanthanum nitrate hexahydrate La(NO3)3·6H2O, Int. J. Developm. Res., 2021, vol. 11, pp. 43318–43321.

    Google Scholar 

  10. Husung, R.D. and Doremus, R.H., The infrared transmission spectra of four silicate glasses before and after exposure to water, J. Mater. Res., 1990, vol. 5, no. 10, pp. 2209–2217.

    Article  CAS  Google Scholar 

  11. Saad, E.A., El Batal, F.H., Fayad, A.M., and Moustafa, F.A., Infrared absorption spectra of some Na-borosilicate glasses containing AgBr and Cu2O (photochromic glasses) in addition to one of transition metal oxide, Silicon, 2011, vol. 3, pp. 85–95.

    Article  CAS  Google Scholar 

  12. Kim, J.M., Chang, S.M., Kong, S.M., Kim, K.-S., Kim, J., and Kim, W.-S. Control of hydroxyl group content in silica particle synthesized by the sol-precipitation process, Ceram. Int., 2009, vol. 35, pp. 1015–1019.

    Article  CAS  Google Scholar 

  13. Tomaszewicz, E., Studies on reactivity in the solid state between some rare-earth metal oxides Ln2O3 where Ln = Y, La, Nd, Sm, Eu, Gd, Dy, Ho, Er, Lu and metal sulfates(VI) MSO4 where M = Ni, Cu, Zn, Cd, J. Mater. Sci., 2006, vol. 41, pp. 1675–1680.

    Article  CAS  Google Scholar 

  14. McDevitt, N.T. and Baun, W.L., Infrared absorption study of metal oxides in the low frequency region (700–240 cm–1), Spectrochim. Acta, Part A, 1964, vol. 20, pp. 799–808.

    Article  CAS  Google Scholar 

  15. Coelho, J., Freire, C., and Hussain, N.S., Structural studies of lead lithium borate glasses doped with silver oxide, Spectrochim. Acta, Part A, 2012, vol. 86, pp. 392–398.

    Article  CAS  Google Scholar 

  16. Machocki, A., Ioannides, T., Stasinska, B., Gac, W., Avgouropoulos, G., Delimaris, D., Grzegorczyk, W., and Pasieczna, S., Manganese–lanthanum oxides modified with silver for the catalytic combustion of methane, J. Catal., 2004, vol. 227, pp. 282–296.

    Article  CAS  Google Scholar 

  17. Srivastava, A., Mishra, G., Singh, J., and Pandey, M.D., A highly efficient nanostructured Au@La2O3 based platform for dopamine detection, Mater. Lett., 2022, vol. 308, 131231. https://doi.org/10.1016/j.matlet.2021.131231

  18. Khan, S.B., Rahman, M.M., Marwani, H.M., Asiri, A.M., and Alamry, K.A., Exploration of silver oxide nanoparticles as a pointer of lanthanum for environmental applications, J. Taiwan Inst. Chem. Eng., 2014, vol. 45, pp.  2770–2776. https://doi.org/10.1016/j.jtice.2014.07.005

    Article  CAS  Google Scholar 

  19. Mu, Q. and Wang, Y., A simple method to prepare Ln(OH)3 (Ln = La, Sm, Tb, Eu, and Gd) nanorods using CTAB micelle solution and their room temperature photolumines-cence properties, J. Alloys Compd., 2011, vol. 509, pp. 2060–2065.

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

Authors thank A.V. Antonov, research associate at the A.P. Karpinsky Russian Geological Research Institute (St. Petersburg, Russia), for analyzing the composite materials by energy-dispersive X-ray spectroscopy.

Funding

This work was supported by the Ministry of Science and High Education of the Russian Federation as part of the state assignment of the Institute of Silicate Chemistry, Russian Academy of Sciences (project АААА-А19-119022290087-1).

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Correspondence to M. A. Girsova.

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Girsova, M.A., Golovina, G.F., Kurilenko, L.N. et al. Infrared Spectroscopy Study of Composite Materials Based on Nanoporous High-Silica Glasses Activated with Silver and Lanthanum Ions. Glass Phys Chem 47 (Suppl 1), S36–S40 (2021). https://doi.org/10.1134/S1087659621070051

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