Abstract
Solid solutions in In2O3–MeO2 (Me = Zr, Sn, Ti) systems based on indium oxide are synthesized by the coprecipitation method. It is found that the ultrasound treatment of the coprecipitation products reduces the degree of agglomeration of the initial particles by a factor of 3 and initiates the crystallization process of the precipitates. Nanocrystal (5–8 nm) precursor powders are obtained at 400°C. The optimal regime for sintering powders based on In2O3 to form a ceramic with a dense microstructure is chosen. The influence of the temperature, alloying additives, and the partial pressure of oxygen on the specific conductivity of indium oxide solid solutions is studied.
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Pal’guev, S.F., Gil’derman, V.K., and Zemtsov, V.I., Vysokotemperaturnye oksidnye elektronnye provodniki dlya elektrokhimicheskikh ustroistv (High Temperature Oxide Electronic Conductors for Electrochemical Devices), Moscow: Nauka, 1990.
Morozova, L.V., Kalinina, M.V., Tikhonov, P.A., Drozdova, I.A., and Shilova, O.A., Electroconducting ceramics based on In2O3, CdO, and LaCrO3, Glass Phys. Chem., 2017, vol. 43, no. 3, p. 276.
Panova, T.I., Arsent’ev, M.Yu., Morozova, L.V., and Drozdova, I.A., Synthesis and investigation of the structure of ceramic nanopowders in the ZrO2–CeO2–Al2O3 system, Glass Phys. Chem, 2010, vol. 36, no. 4, pp. 470–477.
Panova, T.I., Morozova, L.V., and Polyakova, I.G., Synthesis and investigation of properties of nanocrystalline zirconia and hafnia, Glass Phys. Chem., 2011, vol. 37, no. 2, pp. 179–187.
Morozova, L.V., Kalinina, M.V., Arsent’ev, M.Yu., and Shilova, M.V., Influence of cryochemical and ultrasonic processing on the texture and thermal decomposition of xerogels and properties of nanoceramics in the ZrO2–Y2O3–Al2O3 system, Inorg. Mater., 2017, vol. 53, no. 6, pp. 640–647.
Khasanov, O.L., Dvilis, E.S., Polisadova, V.V., and Zykova, A.P., Effekty moshchnogo ul’trazvukovogo vozdeistviya na strukturu i svoistva nanomaterialov, uchebnoe posobie (Effects of Powerful Ultrasonic Action on the Structure and Properties of Nanomaterials), Tomsk: Tomsk. Politekh. Univ., 2008.
Gusev, A.I., Characterization of nanocrystalline materials by the size of particles (grains), Metallofiz. Noveishie Tekhnol., 2008, vol. 30, no. 5, pp. 679–694.
Powder Diffraction File (PDF-2), Release 2007.
Morozova, L.V., Tikhonov, P.A., and Glushkova, V.B., Phase relationships in the ZrO2–In2O3 system, synthesis and physico-chemical properties of solid solutions, Dokl. Akad. Nauk SSSR, 1983, vol. 273, no. 6, pp. 140–144.
Solov’eva, A.E. and Zhdanov, V.A., Features of interaction of indium oxide with SnO2, Neorg. Mater., 1985, vol. 21, no. 6, pp. 957–960.
Morozova, L.V. and Glushkova, V.B., Physico-chemical study of a limiting solid solution based on indium oxide in the system In2O3–TiO2 and indium titanate, Zh. Prikl. Khim., 1992, vol. 65, no. 9, pp. 2138–2140.
Panova, T.I., Morozova, L.V., and Polyakova, I.G., Synthesis and investigation of properties of nanocrystalline zirconia and hafnia, Glass Phys. Chem., 2011, vol. 37, no. 2, pp. 179–187.
Mal’chenko, S.N., Ivanovskaya, M.I., Orlik, D.R., and Ivashkevich, L.S., The growth features of microcrystallites SnO2 obtained from stabilized sols of hydrated tin dioxide, Neorg. Mater., 1992, vol. 28, no. 1, pp. 103–107.
Mal’chenko, S.N., Esmaiel, E., and Ivanovskaya, M.I., The properties of TiO2 obtained from a stabilized sol of titanium hydroxide, Neorg. Mater., 1991, vol. 27, no. 11, pp. 2327−2331.
Khimicheskaya entsiklopediya (Chemical Encyclopedy), Moscow: Bol’sh. Ross. Entsiklopediya, 1998, vol. 5, pp. 34–35.
Morozova, L.V., Kalinina, M.V., Drozdova, I.A., Polyakova, I.G., and Shilova, O.A., Synthesis and study of nanoceramics of the spinel class, Glass Phys. Chem., 2015, vol. 41, no. 6, pp. 650–655.
Morozova, L.V., Tikhonov, P.A., Komarov, A.V., Popov, V.P., and Glushkova, V.B., Electrical properties of solid solutions in ZrO2–In2O3 system, Zh. Prikl. Khim., 1986, vol. 60, no. 6, pp. 1430–1434.
De Witt, J.H.W., The high temperature behavior of In2O3, J. Solid State Chem., 1975, vol. 3, no. 7, pp. 192–200.
Forsh, E.A., Marikutsa, A.V., Martyshov, M.N., Forsh, P.A., Rumyantseva, M.N., Gas’kov, A.M., and Kashkarov, P.K., Charge carrier transport in indium oxide nanocrystals, J. Exp. Theor. Phys., 2010, vol. 111, no. 4, pp. 653–658.
Kröger, F., The Chemistry of Imperfect Crystals, Amsterdam: North-Holland, 1964.
Nikolaenko, Yu.M., Kuzovlev, Yu.E., Medvedev, Yu.V., Mezin, N.I., Bondarchuk, A.N., and Glot, A.B., Electrical conductivity and electric polarization in In2O3–δ: Sr at different oxygen contents, Phys. Solid State, 2011, vol. 53, no. 11, pp. 2220–2226.
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Original Russian Text © L.V. Morozova, I.A. Drozdova, P.A. Tikhonov, 2018, published in Fizika i Khimiya Stekla.
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Morozova, L.V., Drozdova, I.A. & Tikhonov, P.A. Synthesis and Investigation of Solid Solutions Based on Indium Oxide in In2O3–MeO2 (Me = Zr, Sn, Ti) Systems. Glass Phys Chem 44, 192–198 (2018). https://doi.org/10.1134/S1087659618030094
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DOI: https://doi.org/10.1134/S1087659618030094