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Synthesis, structure, and properties of BIFENBVOX

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Abstract

Solid solutions Bi4V2-x Fe x/2Nb x/2O11-δ (х = 0.05–1.0) and Bi4V2-х-y Fe x Nb y O11–δ (with fixed x or y = 0.2 and variable х or y = 0.2–0.5 with step 0.1) were synthesized by the standard ceramic technology in the temperature range 773–1113 K and by mechanochemical activation method using Bi2O3, V2O5 Fe2O3, and Nb2O5 oxides as initial compounds. The formation of solid solutions was studied. Ranges of stability and temperature values of phase transitions for different polymorphous modifications were defined using dylatometric and thermo gravimetric studies. The morphology and the local chemical composition of the ceramic samples were studied. Samples with concentration of dopants x > 0.3 contain two phases; both major and impurity phases are solid solutions of the BIFENBVOX type although the dopants atoms distribution between them is random. The thermal expansion coefficients (TEC) were measured. The electrical conductivity of ceramic samples was investigated in a wide range of temperatures. The highest conductivity values among the studied solid solutions are observed for the sample with a small amount of dopants x = 0.25.

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Acknowledgments

This research project has been supported by UrFU under the Framework Program of development of UrFU through the “Young scientists UrFU” competition.

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Authors and Affiliations

  1. Institute of Natural Sciences, Ural Federal University, 51 Lenin Ave, 620000, Ekaterinburg, Russia

    E. S. Buyanova, M. V. Morozova, Yu. V. Emelyanova & Yu. A. Barikina

  2. Institute for Metallurgy, Ural Branch of the Russian Academy of Sciences, 101 Amundsen Str, 620016, Ekaterinburg, Russia

    S. A. Petrova & R. G. Zaharov

Authors
  1. E. S. Buyanova
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  2. M. V. Morozova
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  3. Yu. V. Emelyanova
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  4. Yu. A. Barikina
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  5. S. A. Petrova
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  6. R. G. Zaharov
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Correspondence to M. V. Morozova.

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Buyanova, E.S., Morozova, M.V., Emelyanova, Y.V. et al. Synthesis, structure, and properties of BIFENBVOX. Ionics 21, 2815–2823 (2015). https://doi.org/10.1007/s11581-015-1483-2

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  • DOI: https://doi.org/10.1007/s11581-015-1483-2

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