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Kinetics of stepwise bulk crystallization of AsSe1.5Sn x (x ≤ 0.28) glasses

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Abstract

The kinetics of stepwise transformations during bulk isothermal crystallization of semiconducting AsSe1.5Sn x (x = 0.13, 0.20, 0.28) glasses has been studied in the temperature range of 210−310°С using 119Sn Mössbauer spectroscopy, XPA, and the density and microhardness measurements of the quenched specimens. The kinetics of the gross bulk crystallization of glasses have been analyzed according to the data on density measurement using the Kolmogorov–Avrami equation, which was generalized on stepwise and incomplete isothermal transformations.

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  1. Department of Chemistry, Kirov St. Petersburg State Forest Technical University, St. Petersburg, 194021, Russia

    E. V. Shkol’nikov

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  1. E. V. Shkol’nikov
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Correspondence to E. V. Shkol’nikov.

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Original Russian Text © E.V. Shkol’nikov, 2017, published in Fizika i Khimiya Stekla.

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Shkol’nikov, E.V. Kinetics of stepwise bulk crystallization of AsSe1.5Sn x (x ≤ 0.28) glasses. Glass Phys Chem 43, 137–145 (2017). https://doi.org/10.1134/S1087659617020158

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