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Magnetochemistry of low-magnetic glass and crystalline materials (Review)

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The theoretical and methodological data on the magnetochemistry of low-magnetic glass and crystalline materials, including chalcogenides, are presented. Based on the methods of the magnetochemistry of glass and crystalline materials, the conclusions about the parameters of chemical bonds in these materials, the distribution of substances added to them, the presence or absence of chemical ordering, and the concentration of intrinsic paramagnetic centers have been made.

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References

  1. Chechernikov, V.I., Magnitnye izmereniya (Magnetic Measurements), Moscow: Mosk. Gos. Univ., 1963.

    Google Scholar 

  2. Baidakov, L.A., Blinov, L.N., Zubenko, Yu.V., Kazenov, B.A., and Strakhov, L.P., Device for study of magnetic susceptibility of solids, Vestn. Leningr. Univ., 1966, no. 1, pp. 40–46.

    Google Scholar 

  3. Tver’yanovich, Yu.S., Device for study of magnetic susceptibility of paramagnetic vapours and matter condensed phase in temperature range 300–1600 K, Vestn. Leningr. Univ., 1978, no. 22, pp. 144–147.

    Google Scholar 

  4. Baidakov, L.A., Magnetochemical study of glassy semiconductors, Extended Abstract of Doctoral Dissertation, Leningrad, 1975.

    Google Scholar 

  5. Baidakov, L.A., Blinov, L.N., and Strakhov, L.P., Magnetic susceptibility of sulfur lead, Izv. Akad. Nauk SSSR, Neorg. Mater., 1967, vol. 3, no. 6, pp. 1083–1084.

    Google Scholar 

  6. Fam Zoan Khan, Blinov, L.N., and Strakhov, L.P., Magnetic susceptibility of V2O5, Sov. Phys. Semicond., 1968, vol. 2, no. 4, pp. 377–381.

    Google Scholar 

  7. Ivanova, E.A., Shul’ts, M.M., and Belyustin, A.A., Electrode properties, magnetic susceptibility and absorption spectra of glasses with vanadium and niobium oxides, Zh. Prikl. Khim., 1996, vol. 39, no. 2, pp. 2488–2496.

    Google Scholar 

  8. Tver’yanovich, Yu.S. and Gutenev, M.S., Magnetokhimiya stekloobraznykh poluprovodnikov (Magnetic Chemistry of Glassy Semiconductors), St. Petersburg: SPb. Gos. Univ., 1997.

    Google Scholar 

  9. Blinov, L.N. and Baidakov, L.A., Application of proton resonance in studies of magnetic properties of amorphous semiconductors, Trudy konferentsii po amorfnym poluprovodnikam (Proceedings of the Conference on Amorphous Semiconductors -78, Pardubice, ChSSR, 1978), vol. 1, pp. 325–327.

    Google Scholar 

  10. Blinov, L.N., Baidakov, L.A., and Korneev, V.R., Study of glassy chalcohenides by NMR methods, in Sovremennye metody EPR i YaMR v khimii tverdogo tela (Modern of ESR and NMR Methods in Solid State Chemistry), Chernogolovka, 1982, pp. 47–48.

    Google Scholar 

  11. Matyas, M., Diamagnetism of glassy semiconductors, Trudy 6-oi mezhdunarodnoi konferentsii po amorfnym i zhidkim poluprovodnikam (Proceedings of the 6th International Conference on Amorphous and Liquid Semiconductors, Leningrad, USSR, 1975), pp. 13–23.

    Google Scholar 

  12. Blinov, L.N., Baidakov, L.A., and Strakhov, L.P., Study of magnetic susceptibility of glassy system As–Se, Izv. Akad. Nauk SSSR, Neorg. Mater., 1968, vol. 4, no. 1, pp. 22–27.

    Google Scholar 

  13. Baidakov, L.A., Blinov, L.N., and Strakhov, L.P., Magnetic susceptibility of semiconductor arsenic chalcogenides in glassy state, in Khimicheskaya svyaz’ v kristallakh (Chemical Bond in Crystals), Minsk: Nauka Tekhnika, 1969, pp. 478–484.

    Google Scholar 

  14. Blinov, L.N., Magnetic properties of chalcogenide glasses (review), Russ. J. Appl. Chem., 1999, vol. 72, no. 7, pp. 1107–1115.

    Google Scholar 

  15. Blinov, L.N. and Orkina, T.N., Dielectric materials based on chalcogenide glassy systems: Properties, ways of preparation, possibilities of application, Russ. J. Appl. Chem., 2000, vol. 73, no. 9, pp. 1561–1571.

    Google Scholar 

  16. Blinov, L.N., Diamagnetism and chemical bond in chalcogenide glasses, in Elektronnyi paramagnitnyi rezonans v tverdofaznykh soedineniyakh (Electronic Paramagnetic Resonance in Solid Phase Compounds), Sverdlovsk: Ural. Otdel. AN SSSR, 1989, pp. 46–49.

    Google Scholar 

  17. Baidakov, L.A. and Blinov, L.N., Investigation of the local structure and long range chemical order of semiconductor chalcogenide glasses by magnetochemical method, in Proceedings of the 8th International Conference on Amorphous and Lignid Semiconductors, Cambridge, USA, 1979, p. YE3.

    Google Scholar 

  18. Blinov, L.N. and Baidakov, L.A., Study perspectives of structural chemical structure of amorphous inorganic polymers by magnetochemistry methods, Tr. Letno-Issled. Inst., 1980, no. 373, pp. 15–18.

    Google Scholar 

  19. Blinov, L.N., Minaev, V.S., and Baidakov, L.A., Magnetic properties and structure of glasses based on chalcogenide of tallium, germanium and phosphorus, in Trudy VII vsesoyuznogo soveshchaniya po stekloobraznomu sostoyaniyu (Proceedings of the 7th All-Union Workshop on Glassy State, Leningrad, 1981), pp. 50–51.

    Google Scholar 

  20. Ananichev, V.A., Blinov, L.N., Funtikov, V.A., Minaev, V.S., and Baidakov, L.A., Magnetic susceptibility of semiconductor glasses based on thallium, germanium and tellurium, Fiz. Khim. Stekla, 1983, vol. 9, no. 3, pp. 314–316.

    Google Scholar 

  21. Blinov, L.N., Baidakov, L.A., Cimpl, Z., and Kosek, F., Magnetic susceptibility of amorphous semiconductors, Sci. Pap. Inst. Chem. Technol., Pardubise, Czechoslovakia, 1981, vol. 44, pp. 29–35.

    Google Scholar 

  22. Novoselov, S.K., Blinov, L.N., Kazenov, B.A., Baidakov, L.A., and Strakhov, L.P., Magnetic properties of monocrystals As2Se3, Vestn. Leningr. Univ., 1970, no. 16, pp. 64–67.

    Google Scholar 

  23. Ivanova, N.I., Gutenev, M.S., Blinov, L.N., and Baidakov, L.A., Magnetokhimicheskoe issledovanie stekol kvazibinarnykh sistem (As(Sb)S1.5)1–x(GeS2)x i (AsS(Se)1.5)1–x(SbS(Se)1.5)x (Magnetochemical study of glasses of quasibinary system (As(Sb)S1.5)1–x(GeS2)x and (AsS(Se)1.5)1–x(SbS(Se)1.5)x), Available from ONIITE, 1986, Cherkassy, no. 656.KhP-86.

    Google Scholar 

  24. Baidakov, L.A., Blinov, L.N., and Gutenev, M.S., Magnetochemical study of atom distribution in system glasses, Fiz. Khim. Stekla, 1985, vol. 11, no. 6, pp. 700–701.

    Google Scholar 

  25. Ivanova, N.I., Baidakov, L.A., Blinov, L.N., and Gutenev, M.S., Magnetochemical study of glassy system germanium-sulfur-selenium, Fiz. Khim. Stekla, 1987, vol. 13, no. 5, pp. 629–630.

    Google Scholar 

  26. Ivanova, N.I., Gutenev, M.S., Blinov, L.N., and Baidakov, L.A., Magnetochemical study of PxS1–x system glasses, Fiz. Khim. Stekla, 1986, vol. 12, no. 5, pp. 629–630.

    Google Scholar 

  27. Blinov, L.N., EPR spectroscopy of chalcogenide glasses, Glass Phys. Chem., 2003, vol. 29, no. 3, pp. 203–223.

    Article  Google Scholar 

  28. Blinov, L.N., Fullerene-containing chalcogenide glassy materials (review), Russ. J. Appl. Chem., 2003, vol. 76, no. 5, pp. 689–699.

    Article  Google Scholar 

  29. Blinov, L.N., Khimiya i fizika khal’kogenidnykh, galogenkhal’kogenidnykh i fullerenkhal’kogenidnykh stekloobraznykh materialov (Chemistry and Physics of Chalcogenide, Halogenchalcogenide and Fullerenchalcogenide Glassy Materials), St. Petersburg: SPb. Gos. Politekh. Univ., 2003.

    Google Scholar 

  30. Dorfman, Ya.G., Diamagnetizm i khimicheskaya svyaz’ (Diamagnetism and Chemical Bond), Moscow: Fizmatgiz, 1960; New York: American Elsevier, 1965.

    Google Scholar 

  31. Vonsovskii, S.V., Magnetizm (Magnetism), Moscow: Nauka, 1971; New York: Wiley, 1971.

    Google Scholar 

  32. Tsukerblat, B.S. and Belinskii, M.I., Magnetokhimiya i radiospektroskopiya obmennykh klasterov (Magnetochemistry and Radiospectroscopy of Exchange Clusters), Chisinau: Stiintsa, 1983.

    Google Scholar 

  33. Selwood, P.W., Magnetochemistry, New York: Interscience, 1956.

    Google Scholar 

  34. Kalinnikov, V.G. and Rakatin, Yu.V., Vvedenie v magnetokhimiyu (Introduction to Magnetochemistry), Moscow: Nauka, 1980.

    Google Scholar 

  35. Bush, G. and Winkler, U., Bestimmung der Charakteristischen Grossen eines Halbleiters, Ergeb. Exakten Naturwiss., 1956, vol. 29, p. 145.

    Article  Google Scholar 

  36. Van-Vleck, J.H., The Theory of Electric and Magnetic Susceptibilities, Oxford: Oxford Univ. Press, 1932.

    Google Scholar 

  37. Vinti, J.P., A relation between the electric and diamagnetic susceptibilities of monatomic gases, Phys. Rev., 1932, vol. 41, no. 15, pp. 813–817.

    Article  Google Scholar 

  38. Ruffa, A.R., Nature of ionic deformations in crystals; application to the analysis of the magnetic properties of the alkali-halide and alkaline-larthoxide crystals, Phys. Rev., 1967, vol. 159, no. 3, pp. 742–754.

    Article  Google Scholar 

  39. Mitskevich, V.V., Deviation from polarizability additivity and diamagnetic susceptibilities in cubic ion crystals, Sov. Phys. Solid State, 1964, vol. 6, no. 3, pp. 557–562.

    Google Scholar 

  40. Sirota, N.N., Nekotorye voprosy khimicheskoi svyazi v poluprovodnikakh i tverdykh telakh (Some Problems of Chemical Binging in Semiconductors and Solids), Minsk: Nauka Tekh., 1965, pp. 12–45.

    Google Scholar 

  41. Beili, F. and Manka, P., Lattice magnetic susceptibility and interatomic bond in semiconductors, in Khimicheskaya svyaz’ v kristallakh (Chemical Bond in Crystals), Minsk: Nauka Tekh., 1969, pp. 39–46.

    Google Scholar 

  42. Mott, N. and Davis, E., Electronic Processes in Non-Crystalline Materials, Oxford: Clarendon, 1971.

    Google Scholar 

  43. Strakhov, L.P., Effect of mechanical treatment on magnetic properties of solids I, in Voprosy elektroniki tverdogo tela (Problems of Solid State Electronics), Leningrad: Nauka, 1974, no. 4, pp. 10–48.

    Google Scholar 

  44. Strakhov, L.P., Effect of mechanical treatment on magnetic properties of solids II, in Voprosy elektroniki tverdogo tela (Problems of Solid State Electronics), Leningrad: Nauka, 1978, no. 7, pp. 115–168.

    Google Scholar 

  45. Hudgens, S., Kastner, M., and Fritzche, H., Diamagnetic susceptibility of tetrahedral semiconductors, Phys. Rev. Lett., 1974, vol. 33, no. 26, pp. 1552–1555.

    Article  Google Scholar 

  46. Chadi, D.J., White, R.M., and Harrison, W.A., Theory of the magnetic susceptibility of tetrahedral semiconductors, Phys. Rev. Lett., 1975, vol. 35, no. 20, pp. 1372–1375.

    Article  Google Scholar 

  47. Garbato, L. and Manca, P., Diamagnetism and chemical bonds in semiconductors, Chem. Phys. Lett., 1977, vol. 48, no. 1, pp. 151–154.

    Article  Google Scholar 

  48. Blinov, L.N., Van Flack diamagnetism and paramagnetism in semiconductors and ionic crystals, Sov. Phys. Semicond., 1983, vol. 17, no. 11, pp. 1261–1262.

    Google Scholar 

  49. Candea, R.M., Hundgens, S.J., and Kastner, M., Ionisity trends in the diamagnetism and its temperature dependence in averade-valence-four semiconductors, Phys. Rev. B, 1978, vol. 18, no. 6, pp. 2733–2738.

    Article  Google Scholar 

  50. Mendelsohn, L.B., Biggs, F., and Mann, J.B., Hartree-Fock diamagnetic susceptibilities, Phys. Rev. A, 1907, vol. 2, no. 4, pp. 1130–1134.

    Article  Google Scholar 

  51. Bonch-Bruevich, V.L., Zvyagin, I.P., Kainer, R., Mironov, A.G., Enderlain, R., and Esser, B., in Elektronnaya teoriya neuporyadochennykh poluprovodnikov (Electronic Theory of Disordered Semiconductors), Moscow: Nauka, 1981.

    Google Scholar 

  52. Andrianov, D.G., Zhukova, L.A., Savel’eva, A.S., and Fistul’, V.I., Mean internal potential and magnetic susceptibility of semiconductor crystals, Sov. Phys. Solid State, 1974, vol. 16, no. 1, pp. 208–211.

    Google Scholar 

  53. Loesche, P. and Grande, S., Chemical shift and Knight-shift in AmBy compounds, in Khimicheskaya svyaz’ v kristallakh (Chemical Bond in Crystals), Minsk: Nauka Tekh., 1969, pp. 208–212.

    Google Scholar 

  54. Tsimpl, Z., Kosek, F., Baidalov, L.A., and Blinov, L.N., Separation of magnetic susceptibility of diamagnetics on diamagnetic and paramagnetic components, Izv. Akad. Nauk SSSR, Neorg. Mater., 1981, vol. 17, no. 12, pp. 2261–2264.

    Google Scholar 

  55. Blinov, L.N., Baidakov, L.A., Cimpl, Z., and Kosek, F., A note on the magnetic susceptibility of tetrahedral semiconductors and ionic crystals, Phys. Status Solidi B, 1984, vol. 121, no. 1, pp. K43–K45.

    Article  Google Scholar 

  56. Mokhammad, Arif and Blinov, L.N., Analysis of the methods for synthesizing halogen-containing chalcogenide glasses, Glass Phys. Chem., 2004, vol. 30, no. 4, pp. 337–341.

    Article  Google Scholar 

  57. Cotton, F.A. and Wilkinson, G., Basic Inorganic Chemistry, New York: Wiley, 1995.

    Google Scholar 

  58. Blinov, L.N. and Bal’makov, M.D., The relationship of the structure and components of magnetic susceptibility of valence electrons in chalcogenide glasses, Fiz. Khim. Stekla, 1983, vol. 9, no. 3, pp. 343–344.

    Google Scholar 

  59. Angus, W.R., Ionic diamagnetic susceptibilities, Proc. R. Soc. London, Ser. A, 1932, vol. 136, no. 830, pp. 569–578.

    Article  Google Scholar 

  60. Batsanov, S.S., Calculation of bond ionicity in crystals by electronegativities aligning method, Zh. Neorg. Khim., 1977, vol. 22, no. 1, pp. 3–8.

    Google Scholar 

  61. Vaipolin, A.A. and Porai-Koshits, E.A., On the structure of glassy chalcogenides of arsenic, Sov. Phys. Solid State, 1963, vol. 5, no. 1, pp. 186–190.

    Google Scholar 

  62. Sayers, D.E., Lytle, F.W., and Stern, E.A., Determination of local structure in amorphous GeSe2, As2S3 and As2Te3 using EXAFS, in Proceedings of the International Conference on Amorphous and Liquids Semiconductors, Leningrad, 1974, pp. 403–410.

    Google Scholar 

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Correspondence to L. N. Blinov.

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Original Russian Text © L.N. Blinov, 2017, published in Fizika i Khimiya Stekla.

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Blinov, L.N. Magnetochemistry of low-magnetic glass and crystalline materials (Review). Glass Phys Chem 43, 1–16 (2017). https://doi.org/10.1134/S1087659617010035

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