Skip to main content
Log in

Regularities of flocculation of silica hydrosol at acrylamide copolymers of the Magnaflok brand

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

The aggregative stability of binary mixtures of silica hydrosols of the Ludox TM brand and solutions of acrylic polymers of the Magnaflok brand have been studied by the methods of viscometry, turbidimetry, electrophoresis, and dynamic light scattering. A decrease in the aggregate stability of colloidal silica and conformational contraction of macromolecular coils with the introduction of the electrolyte leads to the formation of polymer—silica floccules. Flocculation of silica particles at macromolecules proceeds via the mechanism of heterocoagulation. When forming the hybrid polymer—silica particles, the aggregative stability of the dispersed systems grows, the coagulation rate decreases, and the time of gelation increases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Shabanova, N.A. and Sarkisov, P.D., Zol’–gel’ tekhnologiya. Nanodispersnyi kremnezem (Sol–Gel Technology: Nanodispersed Silica), Moscow: BINOM Laboratoriya Znanii, 2012.

    Google Scholar 

  2. Shabanova, N.A., Popov, V.V., and Sarkisov, P.D., Khimiya i tekhnologiya nanodispersnykh oksidov: Uchebnoe posobie (Chemistry and Technology of Nanodispersed Oxides: A Higher Shool Textbook), Moscow: IKTs Akademkniga, 2006.

    Google Scholar 

  3. Moshnikov, V.A., Tairov, Yu.M., Khamova, T.V., and Shilova, O.A., Zol’–gel’ tekhnologiya mikroi nanokompozitov: Uchebnoe posobie (Sol–Gel Technology of Microand Nanocomposites), Shilova, O.A, Ed., St. Petersburg: Lan’, 2013.

  4. Gavrichev, V.D., Dmitriev, A.L., Anfimova, I.N., Kotova, E.I., Nikushchenko, E.M., and Antropova, T.V., Temperature sensors based on silicate porous glasses impregnated by organic compounds, Glass Phys. Chem., 2014, vol. 40, no. 3, pp. 288–290.

    Article  Google Scholar 

  5. Junto Ma, Ping Cui, Lin Zhao, and Ronghua Huang, Synthesis and solution behavior of hydrophobic association water-soluble polymers containing acrylalkyl group, Eur. Polym. J., 2002, vol. 38, no. 8, pp. 1627–1633.

    Article  Google Scholar 

  6. Ke Yang-Chuan, Wei Guang-Yao, and Wang Yi, Preparation, morphology, and properties of nanocomposites of polyacrylamide copolymers with monodisperse silica, Eur. Polym. J., 2008, vol. 44, no. 8, pp. 2448–2457.

    Article  Google Scholar 

  7. Schmidt, G. and Malwitz, M.M., Properties of polymernanoparticle composites, Curr. Opin. Colloid Interface Sci., 2003, vol. 8, no. 1, pp. 103–108.

    Article  Google Scholar 

  8. LeBaron, P.C., Wang, Zh., and Pinnavaia, Th.J., Polymer-layered silicate nanocomposites: An overview, Appl. Clay Sci., 1999, vol. 15, nos. 1–2, pp. 11–29.

    Article  Google Scholar 

  9. Shabanova, N.A. and Belova, I.A., Regularities of associate formation between water-soluble polymers and colloidal silica at early stages of sol–gel processes, Glass Phys. Chem., 2012, vol. 38, no. 2, pp. 254–257.

    Article  Google Scholar 

  10. Shabanova, N.A., Belova, I.A., and Markelova, I.A., Influence of the aggregation activity of binary salts of silica and polymers on the formation of hybrid nanoparticles, in Tezisy dokladov XXII Vserossiiskogo soveshchaniya po neorganicheskim i organosilikatnym pokrytiyam, Sankt-Peterburg, 2014 (Abstracts of Papers of the XXII All-Russian Conference on Inorganic and Organosilicate Coatings), St. Petersburg: Lema, 2014, pp. 12–13.

    Google Scholar 

  11. Losev, I.P. and Fedotova, O.Ya., Praktikum po khimii vysokomolekulyarnykh soedinenii (Practical Works on the Chemistry of High-Molecular Compounds), Moscow: Goskhimizdat, 1962.

    Google Scholar 

  12. Sears, G.W. ffixJr., Determination of specific surface area of colloidal silica by titration with sodium hydroxide, Anal. Chem., 1956, vol. 28, no. 12, pp. 1981–1983.

    Article  Google Scholar 

  13. Wiersema, P.H., Loeb, A.L., and Overbeek, J.Th., Calculation of the electrophoretic mobility of a spherical colloid particle, J. Colloid Interface Sci., 1966, vol. 22, no. 1, pp. 78–99.

    Article  Google Scholar 

  14. Huggins, M.L., The viscosity of dilute solutions of long-chain molecules: IV. Dependence on concentration, J. Am. Chem. Soc., 1942, vol. 64, no. 11, pp. 2716–2718.

    Article  Google Scholar 

  15. Morawetz, H., Macromolecules in Solution, New York: Wiley Interscience, 1965. Translated under the title Makromolekuly v rastvore, Moscow: Mir, 1967.

    Google Scholar 

  16. Klein, J. and Conrad, K.-D., Molecular weight determination of poly(acrylamide) and poly(acrylamide-cosodium acrylate), Macromol. Chem. Phys., 1978, vol. 179, no. 6, pp. 1635–1638.

    Article  Google Scholar 

  17. Von Napper, D.H., Polymeric Stabilization of Colloidal Dispersions, New York: Academic, 1983. Translated under the title Stabilizatsiya kolloidnykh dispersii polimerami, Moscow: Mir, 1986.

    Google Scholar 

  18. Verezhnikov, V.N., Sergeeva, M.N., Shabanova, N.A., and Poyarkova, T.N., Investigation of the aggregation activity of mixtures of polystyrene latex and silica hydrosol using the photon correlation spectroscopy method, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2008, vol. 51, no. 9, pp. 56–58.

    Google Scholar 

  19. Shabanova, N.A. and Sergeeva, M.N., Aggregative stability and structure formation in binary mixtures of synthetic latex and silica hydrosol, Russ. J. Appl. Chem., 2011, vol. 84, no. 8, pp. 1422–1425.

    Article  Google Scholar 

  20. Sergeeva, M.N., Shabanova, N.A., and Verezhnikov, V.N., Specific features of the preparation of hybrid nanocomposites based on synthetic latexes and colloidal silica, in Uspekhi v khimii i khimicheskoi tekhnologii: Sbornik nauchnykh trudov. Tom. XXI (A Collection of Scientific Works: Advances in Chemistry and Chemical Technology: Volume XXI), Moscow: D.I. Mendeleyev University of Chemical Technology of Russia, 2007, no. 4 (72) pp. 26–30.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to I. A. Belova.

Additional information

Original Russian Text © N.A. Shabanova, I.A. Belova, M.N. Markelova, 2015, published in Fizika i Khimiya Stekla.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shabanova, N.A., Belova, I.A. & Markelova, M.N. Regularities of flocculation of silica hydrosol at acrylamide copolymers of the Magnaflok brand. Glass Phys Chem 41, 522–527 (2015). https://doi.org/10.1134/S1087659615050168

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1087659615050168

Keywords

Navigation