Skip to main content
Log in

Synthesis and investigation of nanoceramics based on cobalt metaniobate

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

The precipitation conditions of cobalt and niobium hydroxides have been investigated. Superfine xerogel is obtained by consecutive precipitation of the hydroxides with subsequent freezing of the precipitate at −25°C, from which cobalt metaniobate (CoNb2O6) with the mean size of crystals from 18 to 20 nm is formed in a temperature range from 550 to 650°C. Some electrophysical properties of cobalt metaniobate in the atmospheric air are studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Shevchenko, V.Ya., Grebenshchikov Institute of Silicate Chemistry of the Russian Academy of Sciences: Investigations in the field of nanoworld and nanotechnologies, Ross. Nanotekhnol., 2008, vol. 3, nos. 11–12, pp. 36–45.

    Google Scholar 

  2. Gusev, A.I., Nanometrialy, nanostruktury, nanotekhnologii (Nanomaterials, Nanostructures, and Nanotechnologies), Moscow: Fizmatlit, 2005.

    Google Scholar 

  3. Kovalenko, A.S., Shilova, O.A., Morozova, L.V., Kalinina, M.V., Drozdova, I.A., and Arsent’ev, M.Yu., Specific features of the synthesis and the investigation of nanocrystalline cobalt-nickel spinel, Fiz. Khim. Stekla, 2014, vol. 40, no. 1, pp. 135–145.

    Google Scholar 

  4. Kovalenko, A.S., Shilova, O.A., Morozova, L.V., Kalinina, M.V., Drozdova, I.A., and Arsent’ev, M.Yu., Feature of the synthesis and the study of nanocrystalline cobalt-nickel spinel, Glass Phys. Chem., 2014, vol. 40, no. 4, pp. 106–113.

    Article  Google Scholar 

  5. Belous, A.G., Ovchar, O.V., Kramarenko, A.V., Mishchuk, D.O., Jancar, B., Bezjak, J., and Suvorov, D., Effect of nonstoichiometry on the structure and micro-wave dielectric properties of cobalt metaniobate, Inorg. Mater., 2006, vol. 42, no. 12, pp. 1369–1373.

    Article  Google Scholar 

  6. Duran, P., Villegas, M., and Capel, F., Low-temperature sintering and microstructural development of nanocrystalline Y-TZP powder, J. Eur. Ceram. Soc., 1996, vol. 16, no. 9, pp. 945–952.

    Article  Google Scholar 

  7. Gosudarstvennyi standart Soyuza SSR (State Standard of the Soviet Union), Moscow: Izd. Standartov, 1981.

  8. Arsent’ev, M.Yu., Tikhonov, P.A., Kalinina, M.V., Tsvetkova, I.N., and Shilova, O.A., Synthesis and physicochemical properties of electrode and electrolyte nanocomposites for supercapacitors, Fiz. Khim. Stekla, 2012, vol. 38, no. 5, pp. 653–664.

    Google Scholar 

  9. Arsent’ev, M.Yu., Tikhonov, P.A., Kalinina, M.V., and Andreeva, N.S., Investigation of some physicochemical properties of ceramics, single crystals, and nanofilms based on zirconia, hafnia, and rare-earth oxides, Glass Phys. Chem., 2010, vol. 36, no. 4, pp. 478–483.

    Article  Google Scholar 

  10. Panova, T.I., Arsent’ev, M.Yu., Morozova, L.V., and Drozdova, I.A., Synthesis and investigation of the structure of ceramic nanopowders in the ZrO2-CeO2-Al2O3 system, Fiz. Khim. Stekla, 2010, vol. 36, no. 4, pp. 585–595.

    Google Scholar 

  11. Panova, T.I., Arsent’ev, M.Yu., Morozova, L.V., and Drozdova, I.A., Synthesis and investigation of the structure of ceramic nanopowders in the ZrO2-CeO2-Al2O3 system, Glass Phys. Chem., 2010, vol. 36, no. 4, pp. 470–477.

    Article  Google Scholar 

  12. Panova, T.I., Morozova, L.V., and Polyakova, I.G., Synthesis and investigation of the properties of nanocrystalline zirconium and hafnium dioxides, Fiz. Khim. Stekla, 2011, vol. 37, no. 2, pp. 238–249.

    Google Scholar 

  13. Panova, T.I., Morozova, L.V., and Polyakova, I.G., Synthesis and investigation of the properties of nanocrystalline zirconia and hafnia, Glass Phys. Chem., 2011, vol. 37, no. 2, pp. 179–187.

    Article  Google Scholar 

  14. Tikhonov, P.A., Arsent’ev, M.Yu., Kalinina, M.V., Podzorova, L.I., Il’icheva, A.A., Popov, V.P., and Andreeva, N.S., Preparation and properties of ceramic composites with oxygen ionic conductivity in the ZrO2-CeO2-Al2O3 and ZrO2-Sc2O3-Al2O3 systems, Fiz. Khim. Stekla, 2008, vol. 34, no. 3, pp. 417–422.

    Google Scholar 

  15. Tikhonov, P.A., Arsent’ev, M.Yu., Kalinina, M.V., Popov, V.P., Andreeva, N.S., Podzorova, L.I., and Il’icheva, A.A., Preparation and properties of ceramic composites with oxygen ionic conductivity in the ZrO2-CeO2-Al2O3 and ZrO2-Sc2O3-Al2O3 systems, Glass Phys. Chem., 2008, vol. 34, no. 3, pp. 319–323.

    Article  Google Scholar 

  16. Chaiyo, N. and Vittayakorn, N., Effect of calcination conditions on phase formation of microwave dielectric cobalt niobate (CoNb2O6) powders via a mixed oxide synthesis route, J. Ceram. Process. Res., 2008, vol. 9, no. 4, pp. 381–384.

    Google Scholar 

  17. Shilova, O.A., Antipov, V.N., Tikhonov, P.A., Kruchinina, I.Yu., Arsent’ev, M.Yu., Panova, T.I., Morozova, L.V., Moskovskaya, V.V., Kalinina, M.V., and Tsvetkova, I.N., Ceramic nanocomposites based on oxides of transition metals for ionistors, Fiz. Khim. Stekla, 2013, vol. 39, no. 5, pp. 803–815.

    Google Scholar 

  18. Shilova, O.A., Antipov, V.N., Tikhonov, P.A., Kruchinina, I.Yu., Arsent’ev, M.Yu., Panova, T.I., Morozova, L.V., Moskovskaya, V.V., Kalinina, M.V., and Tsvetkova, I.N., Ceramic nanocomposites based on oxides of transition metals for ionistors, Glass Phys. Chem., 2013, vol. 39, no. 5, pp. 570–578.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to T. L. Egorova.

Additional information

Original Russian Text © M.V. Kalinina, L.V. Morozova, I.I. Khlamov, T.L. Egorova, M.Yu. Arsent’ev, I.A. Drozdova, O.A. Shilova, 2014, published in Fizika i Khimiya Stekla.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kalinina, M.V., Morozova, L.V., Khlamov, I.I. et al. Synthesis and investigation of nanoceramics based on cobalt metaniobate. Glass Phys Chem 40, 578–583 (2014). https://doi.org/10.1134/S108765961405006X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S108765961405006X

Keywords

Navigation