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Thermolysis Synthesis of Pure Phase Nano-Sized Cobalt(II) Oxide from Novel Cobalt(II)-Pyrazole Discrete Nano Coordination Compound

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Abstract

Nano-structures of a new discrete coordination compound of divalent cobalt with the pyrazol (pzH) containing the terminal isothiocyanate anions, [Co(pzH)2(NCS)2] (1), with discrete molecular architecture in solid state was synthesized by a sonochemical method. The new nanostructure was characterized by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray powder diffraction, IR, and elemental analysis. The supramolecular features in these complexes are guided and controlled by weak directional intermolecular interactions. The discrete molecules interact with each other through labile interactions creating a 3D supramolecular framework. The CoO nanoparticles were obtained by thermolysis of 1 at 180 °C with oleic acid as a surfactant.

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Notes

  1. A description of the basis sets and theory level used in this work can be found in the following Reference [36].

References

  1. N. Li, F. Jiang, L. Chen, X. Li, Q. Chen, M. Hong, Chem. Commun. 47, 2327 (2011)

    Article  CAS  Google Scholar 

  2. B. Moulton, M.J. Zaworotko, Chem. Rev. 101, 1629 (2001)

    Article  CAS  Google Scholar 

  3. C.J. Janiak, Dalton Trans. 2003, 2781 (2003)

    Article  Google Scholar 

  4. A.V. Khripun, S.I. Selivanove, V.Y. Kukushkin, M. Haukka, Inorg. Chim. Acta 359, 320 (2006)

    Article  CAS  Google Scholar 

  5. S.K. Seth, Inorg. Chim. Acta 43, 60 (2014)

    CAS  Google Scholar 

  6. J.-M. Lehn, Supramolecular Chemistry, Concepts and Perspectives (VCH, Weinheim, 1995), pp. 139–160

    Book  Google Scholar 

  7. M. Schweiger, S.R. Seidel, A.M. Arif, P.J. Stang, Angew. Chem. Int. Ed. 40, 3467 (2001)

    Article  CAS  Google Scholar 

  8. K. Ohno, A. Nagasawa, T. Fujihara, Dalton Trans. 44, 368 (2015)

    Article  CAS  Google Scholar 

  9. Q.H. Jin, L.L. Song, R. Wong, C.L. Zhang, X. Zuo, X.M. Lu, Polyhedron 29, 441 (2010)

    Article  CAS  Google Scholar 

  10. B.K. Teo, J.C. Calabrese, Inorg. Chem. 15, 2474 (1976)

    Article  CAS  Google Scholar 

  11. A.M. Schuitema, A.F. Stassen, W.L. Driessen, J. Reedijk, Inorg. Chim. Acta 337, 48 (2002)

    Article  CAS  Google Scholar 

  12. I.R. Evans, J.A. Howard, L.E. Howard, J.S. Evans, Z.K. Jacimovic, V.M. Leovac, Inorg. Chim. Acta 357, 4528 (2004)

    Article  CAS  Google Scholar 

  13. B. Soltani, M. Hossaini Sadr, J.T. Engle, C.J. Ziegler, S.W. Joo, Y. Hanifehpour, Trans. Met. Chem. 37, 687 (2012)

    Article  CAS  Google Scholar 

  14. D.-Q. Qi, C.-M. Yu, J.-Z. You, G.-H. Yang, X.-J. Wang, Y.-P. Zhang, J. Mol. Struct. 1100, 421 (2015)

    Article  CAS  Google Scholar 

  15. N. Koch, W. Seichter, M. Mazik, Tetrahedron 71, 8965 (2015)

    Article  CAS  Google Scholar 

  16. A.M. Lopez, M. Guerrero, T. Calvet, M. Font-Bardia, J. Pons, Inorg. Chem. Commun. 55, 51 (2015)

    Article  Google Scholar 

  17. M.H. Sadhu, A. Solanki, S.B. Kumar, Polyhedron 100, 206 (2015)

    Article  CAS  Google Scholar 

  18. A. Solanki, M.H. Sadhu, S.B. Kumar, J. Mol. Struct. 1101, 155 (2015)

    Article  CAS  Google Scholar 

  19. C. Pettinari, A. Tabacaru, S. Galli, Coord. Chem. Rev. 307, 1 (2016)

    Article  CAS  Google Scholar 

  20. C.H. Chen, B.J. Hwanga, J.S. Do, J.H. Weng, M. Venkateswarlu, M.Y. Chenga, R. Santhanam, K. Ragavendran, J.F. Lee, J.M. Chen, D.G. Liu, Electrochem. Commun. 12, 496 (2010)

    Article  CAS  Google Scholar 

  21. N.M. Ahmed, D.E. El-Nashar, S.L. Abd El-Messieh, Mater. Des. 32, 170 (2011)

    Article  CAS  Google Scholar 

  22. P. Torelli, E.A. Soares, G. Renaud, S. Valeri, X.X. Guo, P. Luches, Surf. Sci. 601, 2651 (2007)

    Article  CAS  Google Scholar 

  23. Y. Hanifehpour, B. Mirtamizdoust, S.W. Joo, J. Inorg. Organomet. Polym. 22, 916 (2012)

    Article  CAS  Google Scholar 

  24. B. Mirtamizdoust, S. Ali-Asgari, S.W. Joo, E. Maskani, Y. Hanifehpour, T.H. Oh, J. Inorg. Organomet. Polym. 23, 751 (2013)

    Article  CAS  Google Scholar 

  25. Y. Hanifehpour, B. Mirtamizdoust, A. Morsali, S.W. Joo, Ultrason. Sonochem. 23, 275 (2015)

    Article  CAS  Google Scholar 

  26. Mercury 1.4.1, Copyright Cambridge Crystallographic Data Centre, Cambridge, 2001–2005

  27. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th edn. (Wiley, New York, 1997), pp. 124–126

    Google Scholar 

  28. J.M. Harrowfield, H. Miyamae, B.W. Skelton, A.A. Soudi, A.H. White, Aust. J. Chem. 49, 1165 (1996). and references therein

    Article  Google Scholar 

  29. Bruker AXS Crystal Structure Analysis Package: Bruker, SHELXTL. Version 6.14. Bruker AXS Inc., Madison, Wisconsin, 2000

  30. Bruker AXS Crystal Structure Analysis Package: Bruker, SADABS. Version 2008/1. Bruker AXS Inc., Madison, Wisconsin, 2008

  31. Bruker AXS Crystal Structure Analysis Package: Bruker, XPREP. Version 2008/2. Bruker AXS Inc., Madison, Wisconsin, 2008

  32. Bruker AXS Crystal Structure Analysis Package: . Bruker, SAINT. Version 7.68A. Bruker AXS Inc., Madison,Wisconsin, 2009

  33. Bruker AXS Crystal Structure Analysis Package: Bruker, APEX2. Version 2010.3-0. Bruker AXS Inc., Madison, Wisconsin, 2010

  34. D.T. Cromer, J.T. Waber, International Tables for X-ray Crystallography (Kynoch Press: Birmingham, 1974) Vol. 4, Table 2.2 A

  35. P.J. Hay, W.R.J. Wadt, Chem. Phys. 82, 270 (1985)

    CAS  Google Scholar 

  36. Foresman, J. B.; Frisch, A. E. Exploring Chemistry with Electronic Structure Methods, 2nd ed.; Gaussian Inc.: Pittsburgh, PA, 1996

  37. M.J. Frisch, et al, GAUSSIAN 98, Revision A.9 (Gaussian Inc., Pittsburgh, 1998)

  38. E. Jia, L. Su, P. Liu, M. Jiang, G. Ye, J. Xu, J. Polym. Res. 21, 548 (2014)

    Article  Google Scholar 

  39. L. Aboutorabi, A. Morsali, Ultrason. Sonochem. 18, 407 (2011)

    Article  CAS  Google Scholar 

  40. M.Y. Masoomi, A. Morsali, Coord. Chem. Rev. 256, 2921 (2012)

    Article  CAS  Google Scholar 

  41. B. Mirtamizdoust, B. Shaabani, S.W. Joo, D. Viterbo, G. Croce, Y. Hanifehpour, J. Inorg. Organomet. Polym. 22, 1397 (2012)

    Article  CAS  Google Scholar 

  42. K. Akhbari, A. Morsali, Cryst. Eng. Comm. 13, 2047 (2011)

    Article  CAS  Google Scholar 

  43. R. Bhatt, I. Bhaumik, S. Ganesamoorthy, A.K. Karnal, M.K. Swami, H.S. Patel, P.K. Gupta, Phys. Status Solidi A 209, 176 (2012)

    Article  CAS  Google Scholar 

  44. J.S. Gwag, Y. Sohn, Bull. Korean Chem. Soc. 33, 505 (2012)

    Article  CAS  Google Scholar 

  45. L. Liao, Q. Zhang, Z. Su, Z. Zhao, Y. Wang, Y. Li, X. Lu, D. Wei et al., Nat. Nanotechnol. 9, 69 (2014)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors thank Qom University and Azarbaijan Shahid Madani University for all the supports. This work is funded by the Grant NRF-2015-002423 of the National Research Foundation of Korea.

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Authors and Affiliations

  1. School of Mechanical Engineering, Yeungnam University, Gyeongsan, 712-749, South Korea

    Younes Hanifehpour & Sang Woo Joo

  2. Department of Chemistry, Faculty of Basic Sciences, Azarbaijan Shahid Madani University, Tabriz, Iran

    Behzad Soltani

  3. Department of Chemistry, Faculty of Science, University of Qom, PO Box 37185-359, Qom, Iran

    Babak Mirtamizdoust

  4. Department of Chemical and Biomolecular Engineering, University of Tennessee, Knoxville, TN, 37996, USA

    Bamin Khomami

Authors
  1. Younes Hanifehpour
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  2. Behzad Soltani
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  3. Babak Mirtamizdoust
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  4. Bamin Khomami
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  5. Sang Woo Joo
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Correspondence to Younes Hanifehpour, Babak Mirtamizdoust or Sang Woo Joo.

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Hanifehpour, Y., Soltani, B., Mirtamizdoust, B. et al. Thermolysis Synthesis of Pure Phase Nano-Sized Cobalt(II) Oxide from Novel Cobalt(II)-Pyrazole Discrete Nano Coordination Compound. J Inorg Organomet Polym 26, 335–343 (2016). https://doi.org/10.1007/s10904-016-0326-6

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