Abstract
The local surrounding of copper, antimony, and iodine atoms in multicomponent chalcogenide films CuI-PbI2-As2Se3 and CuI-SbI3-PbI2-As2Se3 deposited from solutions of chalcogenide glass in n-butylamine has been studied by the Mössbauer spectroscopy method on 121Sb and 129I isotopes. It was established that antimony atoms are in the Sb (III) state, where each antimony atom is surrounded by three selenium atoms. Copper atoms are in the Cu (I) state and are surrounded by iodine atoms. The local surrounding of copper, antimony, and iodine atoms in chemically deposited chalcogenide films is analogous to the local surrounding of atoms in the initial chalcogenide glass.
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Original Russian Text © D.L. Baidakov, E.V. Shkol’nikov, V.A. Ryseva, 2013, published in Fizika i Khimiya Stekla.
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Baidakov, D.L., Shkol’nikov, E.V. & Ryseva, V.A. Nuclear γ-resonance spectra and local surrounding of 121Sb and 129I atoms in CuI-PbI2-As2Se3 and CuI-SbI3-PbI2-As2Se3 films. Glass Phys Chem 39, 235–239 (2013). https://doi.org/10.1134/S1087659613030036
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DOI: https://doi.org/10.1134/S1087659613030036