Abstract
Alkali silicate solutions are modified by organic reagents, i.e., monomers (acrylic acid, N,N′-meta(ortho)-phenylene-bismaleimide, and ε-caprolactam), and the ED-20 epoxy resin oligomer. Dispersed organosilicate products are obtained, and their structure and physicochemical properties are investigated. It is demonstrated that the developed materials can be used as fillers for composites
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Inorganic and Organometallic Polymers with Special Properties, Laine, R.M., Ed. (NATO ASI Ser.), New York: Kluwer, 1992, vol. 206.
Andrievskiy, R.A., Thermal Stability of Nanomaterials, Usp. Khim., 2002, vol. 71, no. 10, pp. 967–981.
Kudina, E.F., Kushnerov, D.N., Tyuran, S.I., and Chmykhova, T.G., The Influence of Dispersed Organosilica on Tribotechnical Characteristics of Lubricants, Trenie Iznos, 2003, vol. 24, no. 5, p. 547–553.
Shilova, O.A. and Shilov, V.V., Oxide and Hybrid Organic-Inorganic Nanocomposite Materials Prepared by the Sol-Gel Method: Synthesis, Properties, and Applications, in Nanosistemy, nanomaterialy, nanotekhnologii. Sbornik nauchnykh trudov (Nanosystems, Nanomaterials, and Nanotechnologies: A Collection of Scientific Articles), Shpak, A.P., Ed., Kiev: Akademperiodika, 2003, vol. 1, pp. 9–83 [in Russian].
Pomogailo, A.D., Rozenberg, A.S., and Uflyand, I.E., Nanochastitsy metallov v polimerakh (Metal Nanoparticles in Polymers), Moscow: Khimiya, 2000 [in Russian].
Shabanova, N.A., Popov, V.V., and Sarkisov, P.D., Khimiya i tekhnologiya nanodispersnykh oksidov. Uchebnoe posobie (Chemistry and Technology of Nanodispersed Oxides: A Text Book), Moscow: Akademkniga, 2006.
Khimich, N.N., Koptelova, L.A., and Khimich, G.N., Synthesis and Structure of Nanocomposites in the Aromatic Ester Dendrimer-SiO2 System, Zh. Prikl. Khim. (St. Petersburg), 2003, vol. 76, no. 3, pp. 457–462 [Russ. J. Appl. Chem. (Engl. transl.), 2003, vol. 76, no. 3, pp. 442–447].
Poddenezhnyi, E.N. and Boiko, A.A., Zol’-gel’ sintez opticheskogo kvartsevogo stekla (Sol-Gel Synthesis of Optical Silica Glass), Gomel: Sukhoi State Technical University of Gomel, 2002 [in Russian].
Bronshtein, L.M., Sidorov, S.N., and Valetskii, P.M., Nanostructured Polymeric Systems as Nanoreactors for Nanoparticle Formation, Usp. Khim., 2004, vol. 73, no. 5, pp. 542–557.
Lomakin, S.M. and Zaikov, G.E., Flame-Resistant Polymer Nanocomposites Based on Layered Silicates, Vysokomol. Soedin., Ser. B., 2005, vol. 47, no. 1, pp. 104–120 [Polym. Sci., Ser. B (Engl. transl.), 2005, vol. 47, no. 1, pp. 9–22].
GOST 18307-78 (State Standard): White Carbon: Specifications, Moscow: USSR State Committee on Standards, 1978 [in Russian].
Praktikum po tekhnologii keramiki i ogneuporov (Laboratory Manual on the Technology of Ceramics and Refractories), Poluboyarinov, D.N. and Popil’skii, R.Ya., Eds., Moscow: Gosstoiizdat, 1972, pp. 8–103.
Kudina, E.F. and Burya, A.I., Process of Obtaining and Properties of Active Organic-Inorganic Fillers, in Proceedings of the VI International Conference “Research and Development in Mechanical Industry” (RaDMI-2006), Budva-Montenegro, September 13–17, 2006, CD-ROM: XXII, 1200, xxvi str., ISBN 86-83803-21-X (HTMS), Session B (B-5).
Kudina, E.F., Pleskachevskii, Yu.M., and Burya, A.I., Dispersed Organic-Inorganic Nanocomposite Materials Prepared from Sodium Silicate Solutions: Synthesis, Properties, and Applications, Kompoz. Mater., 2007, vol. 1, no. 1, pp. 8–18.
Kudina, E.F. and Lisovskii, V.V., Modification of Liquid Glass by Acrylic Acid, Zh. Prikl. Khim. (St. Petersburg), 1994, vol. 67, no. 3, pp. 483–486.
Kudina, E.F., Preparation of Dispersed Nanocomposites and Investigation of Their Properties, Konstr. Kompoz. Mater., 2007, no. 3, pp. 75–80.
Biran, V.V., Zlotnikov, I.I., Kudina, E.F., and Lisovskii, V.V., Specific Features of the Interaction of Oligoimides with Aqueous Solutions of Alkali Metal Silicates, Zh. Prikl. Khim. (St. Petersburg), 1990, vol. 63, no. 12, pp. 2515–2519.
Kudina, E.F., Lisovskii, V.V., Tyurina, S.I., and Vegero, N.V., Modification of Silicate Polymer Binder under Microwave Radiation, Dokl. Akad. Nauk Belarusi, 1998, vol. 42, no. 5, pp. 115–119.
Petrova, P.N., Development of Machine-Building Tribotechnical Materials Based on Poly(tetraethylene) and Natural Zeolites from Yakutian Deposits, Extended Abstract of Candidate’s Dissertation, Yakutsk, 2001 [in Russian].
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Original Russian Text © E.F. Kudina, Yu.M. Pleskachevskii, 2009, published in Fizika i Khimiya Stekla.
This article was presented at the XX All-Russia Conference on Temperature-Resistant Functional Coatings, St. Petersburg, Russia, November 27–28, 2007.
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Kudina, E.F., Pleskachevskii, Y.M. Modification of alkali silicate solutions by organic reagents and investigation of the properties of the final products. Glass Phys Chem 35, 436–442 (2009). https://doi.org/10.1134/S1087659609040142
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DOI: https://doi.org/10.1134/S1087659609040142