Abstract
Alkali borosilicate glassy materials, which contain high iron and aluminum oxide concentrations and simulate vitrified high-level wastes of the Savannah River Site (United States), are investigated using X-ray powder diffraction, optical and electron microscopies, and infrared spectroscopy. The materials prepared by induction melting in cold crucibles operating in pilot and industrial facilities at the State Unitary Enterprise “Moscow Research and Production Association Radon” consist of a glass matrix with distributed individual or aggregated crystals of spinel similar in composition to trevorite. The maximum content of the crystalline phase in the glassy material from a “dead volume” of the cold crucible with an industrial size reaches ∼13 vol %. The texture of the glass phase is complex and determined by the direction of flows in cold crucibles under the action of eddy currents, the character of outflow of the glass melt stream during pouring into canisters, and the interaction of the stream with the glass solidified in the canister after preceding pourings. The structure of the anionic motif of the glass phase is predominantly built up of metasilicate chains and boron-oxygen fragments with threefold-coordinated boron.
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Dmitriev, S.A. and Stefanovsky, S.V., Obrashchenie s radioaktivnymi otkhodami (Radioactive-Waste Management), Moscow: Mendeleev Russian University of Chemical Technology, 2000 [in Russian].
Kuz’minov, Yu.S., Lomonova, E.E., and Osiko, V.V., Tugoplavkie materialy iz kholodnogo tiglya (Refractory Materials from a Cold Crucible), Moscow: Nauka, 2004 [in Russian].
Kuz’minov, Yu.S. and Osiko, V.V., Fianity (Fianites), Moscow: Nauka, 2001 [in Russian].
Kobelev, A.P., Stefanovsky, S.V., Lashchenova, T.N., Zakharenko, V.N., Polkanov, M.A., Knyazev, O.A., Herman, C.C., Bickford, D.F.., Holtzscheiter, E.W., Goles, R.W., and Gombert, D., Vitrification of INL and Hanford HLW Surrogates at the SIA Radon Bench-Scale Cold Crucible Unit, in Abstracts of Papers of the 10th International Conference on Environmental Remediation and Radioactive Waste Management (ICEM’05), Glasgow, 2005, p. 182 (Proc. CD-ROM, ID ICEM05-1222).
Kobelev, A.P., Stefanovsky, S.V., Knyasev, O.A., Lashchenova, T.N., Marra, J.C., Holtzscheiter, E.W., and Herman, C.C., Induction Heated Cold Crucible Melter Testing with Troublesome High Level Waste Components, in Proceedings of the 107th American Ceramic Society Meeting, Baltimore, MD, 2005, pp. 159–169.
Kobelev, A.P., Stefanovsky, S.V., Knyazev, O.A., Lashchenova, T.N., Ptashkin, A.G., Polkanov, M.A., Holtzscheiter, E.W., and Marra, J.C., Results of a 50% Waste Loading Vitrification Test Using the Cold Crucible Melter for Savannah River Site, in Proceedings of the Waste Management’06 Conference, Tucson, AZ, 2006, CD-ROM, ID 6127.
Kobelev, A.P., Stefanovsky, S.V., Knyazev, O.A., Lashchenova, T.N., Holtzscheiter, E.W., and Marra, J.C., Cold Crucible Vitrification of Defense Waste Surrogate and Vitrified Product Characterization, Mater. Res. Soc. Symp. Proc., 2006, vol. 932, pp. 353–360.
Kobelev, A.P., Stefanovskii, S.V., Zakharenko, V.N., Polkanov, M.A., Knyazev, O.A., Lashchenova, T.N., Ptashkin, A.G., Holtzscheiter, E., and Marra, J.C., Vitrification of a Surrogate for High-Level Wastes from the Savannah River Plant (USA) on a Cold-Crucible Bench Facility, At. Energ., 2007, vol. 102, no. 4, pp. 225–232 [At. Energy (Engl. transl.), 2007, vol. 102, no. 4, pp. 277–286].
Kobelev, A.P., Stefanovskii, S.V., Zakharenko, V.N., Polkanov, M.A., Knyazev, O.A., Lashchenova, T.N., Ptashkin, A.G., Holtzscheiter, E., and Marra, J.C., Vitrification of a Surrogate for High-Level Wastes from the Savannah River Facility (USA) in a Commercial Cold-Crucible Facility, At. Energ., vol. 102, no. 5, pp. 296–299 [At. Energy (Engl. transl.), 2007, vol. 102, no. 5, pp. 369–374].
Stefanovsky, S.V., Nikonov, B.S., and Marra, J.C., Characterization of the Glass-Ceramic Material Prepared upon Vitrification of an Iron-Containing Surrogate of High-Level Wastes in a Cold Crucible, Fiz. Khim. Stekla, 2007, vol. 33, no. 6, pp. 798–809 [Glass Phys. Chem. (Engl. transl.), 2007, vol. 33, no. 6, pp. 576–586].
Kobelev, A.P., Stefanovskii, S.V., Lebedev, V.V., Polkanov, M.A., Knyazev, O.A., Ptashkin, A.G., Nikonov, B.S., and Marra, J.C., Vitrification of a Simulator of Savannah River Site (USA) Wastes with High Iron and Aluminum Content on Bench and Commercial Facilities with a Cold Crucible, At. Energ., 2008, vol. 104, no. 5, pp. 291–295 [At. Energy (Engl. transl.), 2008, vol. 104, no. 5, pp. 381–386].
Nakamoto, K., Infrared Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1963. Translated under the title Infrakrasnye spektry neorganicheskikh i koordinatsionnykh soedinenii, Moscow: Mir, 1966.
Kolesova, V.A., Vibrational Spectra and Structure of Alkali Borate Glasses, Fiz. Khim. Stekla, 1986, vol. 12, no. 1, pp. 4–13.
Wong, J. and Angell, C.A., Glass Structure by Spectroscopy, New York: Marcel Dekker, 1976.
Anfilogov, V.N., Bykov, V.N., and Osipov, A.A., Silikatnye rasplavy (Silicate Melts), Moscow: Nauka, 2005 [in Russian].
Plyusnina, I.I., Infrakrasnye spektry mineralov (Infrared Spectra of Minerals), Moscow: Moscow State University, 1977 [in Russian].
Appen, A.A., Khimiya stekla (Chemistry of Glass), Leningrad: Khimiya, 1974 [in Russian].
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Original Russian Text © A.A. Akatov, B.S. Nikonov, B.I. Omel’yanenko, S.V. Stefanovsky, J.C. Marra, 2009, published in Fizika i Khimiya Stekla.
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Akatov, A.A., Nikonov, B.S., Omel’yanenko, B.I. et al. Structure of borosilicate glassy materials with high concentrations of sodium, iron, and aluminum oxides. Glass Phys Chem 35, 245–259 (2009). https://doi.org/10.1134/S1087659609030031
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DOI: https://doi.org/10.1134/S1087659609030031