Abstract
A new type of combustion, namely, the combustion of materials without heating of the environment, is described, and the conditions under which this process can occur are analyzed. It is demonstrated that the possibility of occurring the process under consideration depends substantially on the microstructure of the material. The characteristics of the material for which the liquid-phase combustion takes place without an increase in the temperature of the melt are determined using the interaction of a material based on iron and aluminum oxides with the Fe-Zr-O melt as an example.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Gusarov, V.V., Beshta, S.V., Khabensky, V.B., Granovsky, V.S., Almjashev, V.I., Vitol’, S.A., and Krushinov, E.V., Kinetics and Mechanism of the Chemical Interaction of a Sacrificial Material for the Safety System of Nuclear Power Plants with a Core Melt of the Nuclear Reactor, in Trudy Vserossiskoi konferentsii “Protsessy goreniya i vzryva v fizikokhimii i tekhnologii neorganicheskikh materialov” (Proceedings of the All-Russia Conference “Combustion and Explosion Processes in Physical Chemistry and Engineering of Inorganic Materials”), Chernogolovka: ISMAN, 2002, pp. 99–103 [in Russian].
Gusarov, V.V., Almjashev, V.I., Khabensky, V.B., Beshta, S.V., and Granovsky, V.S., Physicochemical Modeling and Analysis of the Interaction between a Core Melt of the Nuclear Reactor and a Sacrificial Material, Fiz. Khim. Stekla, 2005, vol. 31, no. 1, pp. 71–90 [Glass Phys. Chem. (Engl. transl.), 2005, vol. 31, no. 1, pp. 53–66].
Gusarov, V.V., Almjashev, V.I., Khabensky, V.B., Beshta, S.V., and Granovsky, V.S., Interaction of a Material Based on Aluminum and Iron Oxides with a Metal Melt, Zh. Prikl. Khim. (St. Petersburg), 2007, vol. 80, no. 4, pp. 541–548 [Russ. J. Appl. Chem. (Engl. transl.), 2007, vol. 80, no. 4, pp. 528–535].
Gusarov, V.V., Almjashev, V.I., Stolyarova, V.L., Khabensky, V.B., Beshta, S.V., Granovsky, V.S., Aniskevich, Yu.N., Krushinov, E.V., Vitol’, S.A., Saenko, I.V., Sergeev, E.D., Petrov, V.V., Tikhomirov, V.A., Migal’, V.P., Mozhzherin, V.A., Sakulin, V.Ya., Novikov, A.N., Salagina, G.N., and Shtern, E.A., Oxide Material for a Molten-Core Catcher of a Nuclear Reactor, RF Patent 2 212 719, 2003.
Gusarov, V.V., Almjashev, V.I., Khabensky, V.B., Beshta, S.V., and Granovsky, V.S., A New Class of Functional Materials for Devices of Localization of a Core Melt of the Nuclear Reactor, Ross. Khim. Zh., 2005, vol. 49, no. 4, pp. 42–53.
Zel’dovich, Ya.B., Gorenie ugleroda (Combustion of Carbon), Moscow: Nauka, 1949 [in Russian].
Gusarov, V.V., High-Rate Solid-State Chemical Reactions, Zh. Obshch. Khim., 1997, vol. 67, no. 12, pp. 1959–1964.
Blinov, V.I. and Khudyakov, G.N., Diffuzionnoe gorenie zhidkostei (Diffusion Combustion of Liquids), Moscow: USSR Academy of Sciences, 1961 [in Russian].
Williams, F.A., Combustion Theory, London: Addison-Wesley, 1964. Translated under the title Teoriya goreniya, Moscow: Nauka, 1971.
Williams, F.A., Theory of Combustion in Laminar Flows, Ann. Rev. Fluid Mech., 1971, vol. 3, pp. 171–188.
Pokhal, P.F., Belyaev, A.F., Frolov, Yu.V., Logachev, V.S., and Korotkov, A.I., Goreniya poroshkoobraznykh metallov v aktivnykh sredakh (Combustion of Powdered Metals in Reactive Media), Moscow: Nauka, 1972 [in Russian].
Zel’dovich, Ya.B., Barenblat, G.I., Librovich, V.B., and Makhvelidze, G.M., Matematicheskaya teoriya goreniya i vzryva (Mathematical Theory of Combustion and Explosion), Moscow: Nauka, 1980 [in Russian].
Frank-Kamenetskii, D.A., Diffuziya i teploperedacha v khimicheskoi kinetike (Diffusion and Heat Transfer in Chemical Kinetics), Moscow: Nauka, 1987 [in Russian].
Glansdorff, P. and Prigogine, I., Thermodynamic Theory of Structure, Stability, and Fluctuations, New York: Wiley, 1971. Translated under the title Termodinamicheskaya teoriya struktury, ustoichivosti i fluktuatsii, Moscow: Mir, 1973.
Lykov, A.V., Teplomassoobmen. Spravochnik (Heat and Mass Transfer: A Handbook), Moscow: Energy, 1978 [in Russian].
Zel’dovich, Ya.B. and Frank-Kamenetskii, D.A., On the Theory of Uniform Flame Propagation, Dokl. Akad. Nauk SSSR, 1938, vol. 19, pp. 693–798.
Zel’dovich, Ya.B., On the Theory of Flame Propagation, Zh. Fiz. Khim., 1948, vol. 22, no. 1, pp. 27–48.
Almjashev, V.I., Beshta, S.V., Granovsky, V.S., and Gusarov, V.V., Application of the Finite Automation Method to the Kinetic Analysis of the Chemical Interaction between Materials and Melts, in Trudy Nauchnoprakticheskogo soveshchaniya “Komp’yuternoe modelirovanie pri optimizatsii tekhnologicheskikh protsessov elektrotermicheskikh proizvodstv” (Proceedings of the Scientific and Practical Workshop “Computer Simulation for Optimizing Technological Processes of Electrothermal Production”), St. Petersburg: St. Petersburg State Technical University (Technological Institute), 2000, pp. 39–56 [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.V. Gusarov, V.I. Almjashev, V.B. Khabensky, S.V. Beshta, V.S. Granovsky, 2007, published in Fizika i Khimiya Stekla.
Rights and permissions
About this article
Cite this article
Gusarov, V.V., Almjashev, V.I., Khabensky, V.B. et al. Physicochemical simulation of the combustion of materials with the total endothermal effect. Glass Phys Chem 33, 492–497 (2007). https://doi.org/10.1134/S1087659607050112
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1087659607050112