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Selective Hydrogenation of 1,3-Pentadiene on Mono- and Bimetallic Nickel and Palladium Catalysts

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Abstract

The catalytic properties of palladium and nickel, including sulfidized catalysts, as well as bimetallic Pd-Ag catalysts in the hydrogenation of 1,3-pentadiene to pentenes have been studied. Sulfidation of nickel and palladium catalysts leads to a significant increase in olefin selectivity. Palladium catalysts are more active at low reaction temperatures, however, sulfidized Ni catalysts are not inferior to palladium ones in olefin selectivity and productivity. Palladium catalysts with an ultralow palladium concentration (0.04 wt %) have been developed, which are an order of magnitude more potent than the other studied catalysts in terms of turnover frequency.

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Funding

The work was financially supported by the Ministry of Science and Higher Education of the Russian Federation project no. 075-15-2021-959 (13.2251.21.0048, project unique identification number RF----225121X0048).

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Authors and Affiliations

  1. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    L. M. Kustov, A. L. Tarasov & A. L. Kustov

  2. Chemical Department, Lomonosov Moscow State University, 119992, Moscow, Russia

    L. M. Kustov & A. L. Kustov

  3. Tsinghua University, 100084, Beijing, China

    Boqing Xu

  4. East China University of Science and Technology, 200237, Shanghai, China

    Xuezhi Duan

  5. School of Chemical Engineering, Nanjing University of Technology, 210094, Nanjing, China

    Yanhui Yang

Authors
  1. L. M. Kustov
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  2. A. L. Tarasov
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  3. Boqing Xu
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  4. Xuezhi Duan
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  5. Yanhui Yang
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  6. A. L. Kustov
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Corresponding author

Correspondence to L. M. Kustov.

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The authors declare no conflict of interest.

Additional information

Translated from Zhurnal Organicheskoi Khimii, 2022, Vol. 58, No. 5, pp. 526–531 https://doi.org/10.31857/S051474922205010X.

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Kustov, L.M., Tarasov, A.L., Xu, B. et al. Selective Hydrogenation of 1,3-Pentadiene on Mono- and Bimetallic Nickel and Palladium Catalysts. Russ J Org Chem 58, 706–709 (2022). https://doi.org/10.1134/S1070428022050104

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  • DOI: https://doi.org/10.1134/S1070428022050104

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