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Synthesis of Acetylenic [Chloro(iodo)methyl]silanes and 2-Sulfanylbenzothiazoles Based Thereon

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Abstract

Bromomagnesium derivatives of ethynylsilanes [Me4–nSi(C≡CMgBr)n, n = 1–3] reacted with chloro­(chloromethyl)dimethylsilane to give the corresponding (chloromethyl)(ethynyl)silanes [Me4–nSi(C≡CSiMe2CH2Cl)n, n = 1–3] which were converted to iodomethyl analogs by exchange reaction with sodium iodide. The reaction of the resulting (iodomethyl)(ethynyl)silanes with 1,3-benzothiazole-2-thiol afforded new ethynylsilylmethyl thiazolyl sulfides.

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ACKNOWLEDGMENTS

This study was performed using the facilities of the Baikal joint analytical center (Siberian Branch, Russian Academy of Sciences).

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Authors and Affiliations

  1. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 664033, Irkutsk, Russia

    N. O. Yarosh, L. V. Zhilitskaya & I. A. Dorofeev

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  1. N. O. Yarosh
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  2. L. V. Zhilitskaya
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  3. I. A. Dorofeev
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Correspondence to L. V. Zhilitskaya.

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The authors declare the absence of conflict of interest.

Additional information

Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 10, pp. 1444–1450 https://doi.org/10.31857/S0514749221100104.

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Yarosh, N.O., Zhilitskaya, L.V. & Dorofeev, I.A. Synthesis of Acetylenic [Chloro(iodo)methyl]silanes and 2-Sulfanylbenzothiazoles Based Thereon. Russ J Org Chem 57, 1632–1637 (2021). https://doi.org/10.1134/S107042802110109

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