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Synthesis and Spectral and Coordination Properties of meso-Tetraarylporphyrins

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Abstract

5,10,15,20-Tetrakis(3,5-dibromophenyl)porphyrin and 5,10,15,20-tetrakis(3-bromo-4-methoxy-phenyl)porphyrin have been synthesized, and their complexing properties with respect to Pd2+ ion in acetonitrile at 308–328 K have been studied by spectrophotometry. The synthesized compounds were characterized by UV-Vis, 1H NMR, and mass spectra. The effect of substitueras in the meso-phenyl rings of the ligands on their spectral and coordination properties was estimated in comparison to 5,10,15,20-tetraphenylporphyrin.

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Acknowledgments

This study was performed using the equipment of the “Upper Volga Regional Center for Physicochemical Srudies” joint center at the Krestov Institute of Solution Chemistry, Russian Academy of Sciences.

Funding

This study was financially support by the Russian Foundation for Basic Research (project no. 19-03-00078A).

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, 153045, Russia

    Yu. B. Ivanova & N. Zh. Mamardashvili

  2. Ivanovo State University of Chemistry and Technology, Ivanovo, 153460, Russia

    A. S. Semeikin & S. G. Pukhovskaya

Authors
  1. Yu. B. Ivanova
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  2. A. S. Semeikin
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  3. S. G. Pukhovskaya
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  4. N. Zh. Mamardashvili
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Corresponding author

Correspondence to Yu. B. Ivanova.

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Conflict of Interests

The authors declare the absence of conflict of interests.

Russian Text © The Author(s), 2019, published in Zhurnal Organicheskoi Khimii, 2019, Vol. 55, No. 12, pp. 1888–1894.

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Ivanova, Y.B., Semeikin, A.S., Pukhovskaya, S.G. et al. Synthesis and Spectral and Coordination Properties of meso-Tetraarylporphyrins. Russ J Org Chem 55, 1878–1883 (2019). https://doi.org/10.1134/S107042801912011X

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  • DOI: https://doi.org/10.1134/S107042801912011X

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