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New Reaction of Dimethylformamide with Acrylic Acid

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Abstract

A new homogeneous reaction of dimethylformamide (DMF) with acrylic acid was studied. The reaction afforded previously unknown 3-[2-carboxyethyl(dimethyl)azaniumyl]propanoate and carbon monoxide. The product structure was determined by 1H and 13C NMR spectroscopy, X-ray diffraction, and elemental analysis, and evolution of gaseous carbon monoxide was confirmed by GC/MS. The kinetic parameters of the described reaction and its overall order were determined.

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Authors and Affiliations

  1. “AhmadullinS Science and Technologies”, Research and Development Center, Kazan, 420029, Russia

    A. G. Akhmadullina & R. M. Akhmadullin

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, 420088, Russia

    A. S. Gazizov & A. T. Gubaidullin

  3. Kazan National Research Technological University, Kazan, 420015, Russia

    A. V. Lisin

Authors
  1. A. G. Akhmadullina
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  2. R. M. Akhmadullin
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  3. A. S. Gazizov
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  4. A. T. Gubaidullin
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  5. A. V. Lisin
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Corresponding author

Correspondence to A. G. Akhmadullina.

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Conflict of Interests

The authors declare the absence of conflict of interests.

Russian Text © The Author(s), 2019, published in Zhurnal Organicheskoi Khimii, 2019, Vol. 55, No. 12, pp. 1870–1876.

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Akhmadullina, A.G., Akhmadullin, R.M., Gazizov, A.S. et al. New Reaction of Dimethylformamide with Acrylic Acid. Russ J Org Chem 55, 1864–1868 (2019). https://doi.org/10.1134/S107042801912008X

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  • DOI: https://doi.org/10.1134/S107042801912008X

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