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Chemistry of Iminofurans: XV. Decyclization of Ethyl 2-[5-Aryl-2-oxofuran-3(2H)-ylideneamino]-4,5,6,7-tetrahydro-1-benzothiophene-3-carboxylates by the Action of Secondary Amines

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Abstract

Ethyl 2-[5-aryl-2-oxofuran-3(2H)-ylideneamino]-4,5,6,7-tetrahydro-1-benzothiophene-3-carboxylates reacted with secondary amines to give 4-aryl-2-(thiophen-2-yl)-4-oxobutanamides, whereas their reaction with piperazine afforded N,N′-disubstituted piperazine derivatives regardless of the reactant ratio.

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Authors and Affiliations

  1. Perm National State Research University, ul. Bukireva 15, Perm, 614990, Russia

    A. Yu. Vasileva, V. Yu. Vaganov, S. A. Shipilovskikh & A. E. Rubtsov

Authors
  1. A. Yu. Vasileva
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  2. V. Yu. Vaganov
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  3. S. A. Shipilovskikh
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  4. A. E. Rubtsov
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Corresponding author

Correspondence to A. E. Rubtsov.

Additional information

Original Russian Text © A.Yu. Vasileva, V.Yu. Vaganov, S.A. Shipilovskikh, A.E. Rubtsov, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 4, pp. 581–586.

For communication XIV, see [1].

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Vasileva, A.Y., Vaganov, V.Y., Shipilovskikh, S.A. et al. Chemistry of Iminofurans: XV. Decyclization of Ethyl 2-[5-Aryl-2-oxofuran-3(2H)-ylideneamino]-4,5,6,7-tetrahydro-1-benzothiophene-3-carboxylates by the Action of Secondary Amines. Russ J Org Chem 54, 582–587 (2018). https://doi.org/10.1134/S1070428018040115

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