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Methylation of mono- and dicarboxylic acids with dimethyl carbonate catalyzed with binder-free zeolite NaY

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Abstract

Synthesis of methyl mono- and dicarboxylates was developed consisting in treating the corresponding acids with dimethyl carbonate in the presence of a heterogenic catalyst, crystalline aluminosilicate whose mechanically strong granules to 90–95% were built of crystal aggregates of zeolite Y with modulus of about 5.0 in the Na-form. Optimum catalyst and reagents ratio and the reaction conditions were found for the preparation in high yields of methyl esters of mono- and dicarboxylic acids.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Russia

    R. I. Khusnutdinov, N. A. Shchadneva, Yu. Yu. Mayakova, Yu. S. Konovalova, A. N. Khazipova & B. I. Kutepov

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  1. R. I. Khusnutdinov
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  2. N. A. Shchadneva
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  3. Yu. Yu. Mayakova
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  4. Yu. S. Konovalova
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  5. A. N. Khazipova
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  6. B. I. Kutepov
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Corresponding author

Correspondence to B. I. Kutepov.

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Original Russian Text © R.I. Khusnutdinov, N.A Shchadneva, Yu.Yu. Mayakova, Yu.S. Konovalova, A.N. Khazipova, B.I. Kutepov, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 2, pp. 177–181.

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Khusnutdinov, R.I., Shchadneva, N.A., Mayakova, Y.Y. et al. Methylation of mono- and dicarboxylic acids with dimethyl carbonate catalyzed with binder-free zeolite NaY. Russ J Org Chem 53, 163–168 (2017). https://doi.org/10.1134/S107042801702004X

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  • DOI: https://doi.org/10.1134/S107042801702004X

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