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Kinetic and quantum chemical studies of the mechanism of dehydrochlorination of 2,2-diaryl-1,1,1-trichloroethanes with nitrite ions

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Abstract

The E2 mechanism has been proposed for the dehydrochlorination of 2,2-diaryl-1,1,1-trichloroethanes with nitrite ion, leading to 2,2-diaryl-1,1-dichloroethenes, on the basis of experimental kinetic study and quantum chemical simulation.

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Authors and Affiliations

  1. Demidov Yaroslavl State University, ul. Sovetskaya 14, Yaroslavl, 150000, Russia

    V. N. Kazin, M. B. Kuzhin, A. V. Sirik & E. A. Guzov

Authors
  1. V. N. Kazin
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  2. M. B. Kuzhin
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  3. A. V. Sirik
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  4. E. A. Guzov
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Correspondence to V. N. Kazin.

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Original Russian Text © V.N. Kazin, M.B. Kuzhin, A.V. Sirik, E.A. Guzov, 2016, published in Zhurnal Organicheskoi Khimii, 2016, Vol. 52, No. 9, pp. 1290–1294.

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Kazin, V.N., Kuzhin, M.B., Sirik, A.V. et al. Kinetic and quantum chemical studies of the mechanism of dehydrochlorination of 2,2-diaryl-1,1,1-trichloroethanes with nitrite ions. Russ J Org Chem 52, 1277–1281 (2016). https://doi.org/10.1134/S1070428016090049

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  • DOI: https://doi.org/10.1134/S1070428016090049

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