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Synthesis and steric structure of 3′,3′,5′-trimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]octane] and 3′,5′-dimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]oct[3]ene]

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Abstract

Reactions of hexafluoroacetone with 4-(1,3,2-benzodioxaphosphol-2-yloxy)-4-methylpentan-2-one and 4-(1,3,2-benzodioxaphosphol-2-yloxy)pent-3-en-2-one afforded cage spiro phosphoranes with a phosphorus-carbon bond, 3′,3′,5′-trimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]-trioxa[1λ5]phosphabicyclo[3.2.1]octane] and 3′,5′-dimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]oct[3]ene], whose structure was determined by X-ray analysis.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia

    V. F. Mironov, T. A. Baronova, E. V. Mironova, M. N. Dimukhametov, D. B. Krivolapov & L. M. Abdrakhmanova

  2. Kazan Federal University, ul. Kremlevskaya 18, Kazan, 420008, Tatarstan, Russia

    V. F. Mironov & E. V. Mironova

Authors
  1. V. F. Mironov
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  2. T. A. Baronova
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  3. E. V. Mironova
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  4. M. N. Dimukhametov
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  5. D. B. Krivolapov
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  6. L. M. Abdrakhmanova
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Correspondence to V. F. Mironov.

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Dedicated to Full Member of the Russian Academy of Sciences V.I. Minkin on his 80th anniversary

Original Russian Text © V.F. Mironov, T.A. Baronova, E.V. Mironova, M.N. Dimukhametov, D.B. Krivolapov, L.M. Abdrakhmanova, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 3, pp. 415–424.

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Mironov, V.F., Baronova, T.A., Mironova, E.V. et al. Synthesis and steric structure of 3′,3′,5′-trimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]octane] and 3′,5′-dimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]oct[3]ene]. Russ J Org Chem 51, 401–410 (2015). https://doi.org/10.1134/S1070428015030203

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  • DOI: https://doi.org/10.1134/S1070428015030203

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