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Reaction of dimethyl disulfide with thiophene catalyzed by zeolite

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Abstract

Reaction of dimethyl disulfide with thiophene under the action of highly siliceous zeolite at 180–350°C and contact time 0.6–14 s resulted in formation of thioalkylation products, 2-(methylsulfanyl)- and 2,5-bis(methylsulfanyl)thiophenes and also alkylated derivatives, 2-methyl-, 2,5-dimethyl-, and 2,3,4-trimethylthiophenes.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    A. V. Mashkina & L. N. Khairulina

Authors
  1. A. V. Mashkina
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  2. L. N. Khairulina
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Corresponding author

Correspondence to A. V. Mashkina.

Additional information

Original Russian Text © A.V. Mashkina, L.N. Khairulina, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 2, pp. 229–231.

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Mashkina, A.V., Khairulina, L.N. Reaction of dimethyl disulfide with thiophene catalyzed by zeolite. Russ J Org Chem 51, 217–220 (2015). https://doi.org/10.1134/S1070428015020141

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  • DOI: https://doi.org/10.1134/S1070428015020141

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