Abstract
A procedure has been developed for the intercalation of pyrrole into nanocavities of a metal-organic coordination polymer, chromium terephthalate MIL-101, and oxidative polymerization of pyrrole has been accomplished. The new composite nanomaterial thus obtained, polypyrrole@MIL-101, has been characterized by the data of elemental analysis, X-ray powder diffraction, thermal analysis, and scanning electron microscopy. Its specific surface area has been estimated at 1700 m2/g according to Brunauer-Emmett-Teller.
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Original Russian Text © S.B. Aliev, E.A. Maksimovskii, D.G. Samsonenko, D.N. Dybtsev, V.P. Fedin, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 4, pp. 522–524.
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Aliev, S.B., Maksimovskii, E.A., Samsonenko, D.G. et al. Synthesis of polypyrrole intercalated into channels of nanoporous metal-organic coordination polymer. Russ J Org Chem 50, 510–512 (2014). https://doi.org/10.1134/S1070428014040113
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DOI: https://doi.org/10.1134/S1070428014040113