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Luminescence properties of mesoporous chromium(III) terephthalate and inclusion compounds of cluster complexes

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Abstract

The luminescence properties of mesoporous chromium(III) terephthalate [Cr3O(C8H4O4)3F(H2O)2] (MIL-101) were discovered, and the luminescence spectra were detected at temperatures from 20 to 290 K. By the interaction of MIL-101 with solutions of anionic clusters [Mo6Cl14]2- (Mo6) and [Re6S8(CN)6]4- (Re6) new hybrid materials Mo6MIL-101 and Re6MIL-101 were synthesized, the nanoporous framework of which contains ca. 3.5 and 1.5 clusters per cage, respectively. The synthesized hybrid materials possess the luminescence properties different from those of the initial framework and cluster complexes.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    K. A. Kovalenko, D. N. Dybtsev & V. P. Fedin

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    K. A. Kovalenko, D. N. Dybtsev & V. P. Fedin

  3. Institute of Nanotechnology, Forschungszentrum Karlsruhe, P.O. Box 3640, D-76021, Karlsruhe, Germany

    S. F. Lebedkin

Authors
  1. K. A. Kovalenko
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  2. D. N. Dybtsev
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  3. S. F. Lebedkin
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  4. V. P. Fedin
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Corresponding author

Correspondence to V. P. Fedin.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 727–730, April, 2010.

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Kovalenko, K.A., Dybtsev, D.N., Lebedkin, S.F. et al. Luminescence properties of mesoporous chromium(III) terephthalate and inclusion compounds of cluster complexes. Russ Chem Bull 59, 741–744 (2010). https://doi.org/10.1007/s11172-010-0155-7

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  • DOI: https://doi.org/10.1007/s11172-010-0155-7

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