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Effect of pressure on the rate of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene

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Abstract

The enthalpy, entropy, and volume of activation and volume of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene in 1,2-dichloroethane have been determined. Possible factors responsible for the sharp difference between the volumes of activation and reaction are considered.

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Authors and Affiliations

  1. Butlerov Institute of Chemistry, Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, Kazan, 420008, Tatarstan, Russia

    V. D. Kiselev, D. A. Kornilov, E. A. Kashaeva & L. N. Potapova

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia

    A. I. Konovalov

Authors
  1. V. D. Kiselev
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  2. D. A. Kornilov
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  3. E. A. Kashaeva
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  4. L. N. Potapova
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  5. A. I. Konovalov
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Corresponding author

Correspondence to V. D. Kiselev.

Additional information

Original Russian Text © V.D. Kiselev, D.A. Kornilov, E.A. Kashaeva, L.N. Potapova, A.I. Konovalov, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 4, pp. 503–506.

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Kiselev, V.D., Kornilov, D.A., Kashaeva, E.A. et al. Effect of pressure on the rate of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene. Russ J Org Chem 50, 489–493 (2014). https://doi.org/10.1134/S1070428014040071

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  • DOI: https://doi.org/10.1134/S1070428014040071

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