Abstract
The rate of the reaction between 9,10-anthracenedimethanol and maleic anhydride in 1,4-dioxane, acetonitrile, trichloromethane, and toluene is studied at 25, 35, 45°C in the pressure range of 1–1772 bar. The rate constants, enthalpies, entropies and activation volumes are determined. It is shown that the rate of reaction with 9,10-anthracenedimethanol is approximately one order of magnitude higher than with 9-anthracenemethanol.
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Original Russian Text © V.D. Kiselev, D.A. Kornilov, O.V. Anikin, L.I. Latypova, A.I. Konovalov, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 3, pp. 446–449.
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Kiselev, V.D., Kornilov, D.A., Anikin, O.V. et al. Effect of hydrostatic pressure, temperature, and solvent on the rate of the Diels–Alder reaction between 9,10-anthracenedimethanol and maleic anhydride. Russ. J. Phys. Chem. 91, 464–467 (2017). https://doi.org/10.1134/S0036024417030128
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DOI: https://doi.org/10.1134/S0036024417030128