Abstract
Conformational analysis of bis(2-phenylalkyl)phosphine selenides was performed by the dipole moment method and quantum-chemical calculations. Bis(2-phenylpropyl)phosphine selenide was found to exist as a mixture of several conformers, the most energetically favorable of which being characterized by gauche (non-eclipsed) orientation of the P=Se and \(C_{sp^3 } - C_{sp^3 } \) bonds.
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Original Russian Text © Ya.A. Vereshchagina, D.V. Chachkov, A.Z. Alimova, E.A. Ishmaeva, S.F. Malysheva, 2012, published in Zhurnal Organicheskoi Khimii, 2012, Vol. 48, No. 10, pp. 1324–1326.
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Vereshchagina, Y.A., Chachkov, D.V., Alimova, A.Z. et al. Conformational analysis of secondary arylalkylphosphine selenides. Russ J Org Chem 48, 1320–1322 (2012). https://doi.org/10.1134/S1070428012100090
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DOI: https://doi.org/10.1134/S1070428012100090