Abstract
Reactions of dimedone and ethyl acetoacetate with 1,2-epoxy-3-chloropropane in the presence of K2CO3 in DMSO medium were investigated. The reaction of 1,2-epoxy-3-chloropropane with ethyl acetoacetate afforded ethyl 5-hydroxy-2-methyl-5,6-dihydro-4H-pyran-3-carboxylate, with dimedone, 3-(1′,2′-epoxypropyloxy)-5,5-dimethyl-cyclohex-2-en-1-one.
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Nagiev, F.N., Magerramov, A.M., Mamedov, I.G., Kurbanov, A.V., and Allakhverdiev, M.A., Zhurnal Khimicheskikh Problem, 2006, vol. 1, p. 99.
Muthusamy, S. and Gnanaprakasam, B., Tetrahedron, 2005, vol. 46, p. 635.
Marchetti, P., Tetrahedron, 2003, vol. 46, p. 4121.
Zhu, J., You, L., Zhao, S.X., White, B., Chenb, J.G., and Skonezny, P.M., Tetrahedron, 2002, vol. 43, p. 7585.
Song, Z., Reiner, J., and Zhao, K., Tetrahedron, 2004, vol. 45, p. 3953.
Trabelsi, H., Szonyi, F., and Geribaldi, S., J. Fluor. Chem., 2001, vol. 107, p. 177.
Meciarova, M., Kiripolsky, M., and Toma, S., Ultrasonics Sono-Chemistry, 2005, vol. 12, p. 401.
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Original Russian Text © A.M. Magerramov, F.N. Nagiev, I.G. Mamedov, M.A. Allakhverdiev, 2010, published in Zhurnal Organicheskoi Khimii, 2010, Vol. 46, No. 11, pp. 1652–1654.
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Magerramov, A.M., Nagiev, F.N., Mamedov, I.G. et al. Investigation of reaction of dimedone and ethyl acetoacetate with 1,2-epoxy-3-chloropropane. Russ J Org Chem 46, 1658–1661 (2010). https://doi.org/10.1134/S1070428010110072
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DOI: https://doi.org/10.1134/S1070428010110072