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Pincer ligands based on α-amino acids: III. New ligands based on 4-substituted phenols and their copper complexes. Enantioselective recognition of tyrosine

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Abstract

Reactions of L-methionine, L-serine, and L-valine with 5-substituted-2-hydroxybenzene-1,3-dicarbaldehydes gave a series of chiral Schiff base pincer ligands which were reduced to the corresponding diamines. The new Schiff base ligands reacted with copper(II) chloride to form dinuclear copper complexes which were found to be capable of recognizing tyrosine enantiomers in aqueous solution. The structure of the complexes was determined on the basis of their spectral parameters.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Vorob’evy gory 1, Moscow, 119992, Russia

    N. E. Borisova, M. Yu. Seliverstov, E. A. Borisov & M. D. Reshetova

  2. Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, ul. Surganova 13, Minsk, 220072, Belarus

    V. A. Knizhnikov & T. G. Gulevich

Authors
  1. N. E. Borisova
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  2. V. A. Knizhnikov
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  3. T. G. Gulevich
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  4. M. Yu. Seliverstov
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  5. E. A. Borisov
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  6. M. D. Reshetova
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Corresponding author

Correspondence to N. E. Borisova.

Additional information

Original Russian Text © N.E. Borisova, V.A. Knizhnikov, T.G. Gulevich, M.Yu. Seliverstov, E.A. Borisov, M.D. Reshetova, 2009, published in Zhurnal Organicheskoi Khimii, 2009, Vol. 45, No. 3, pp. 377–385.

For communication II, see [1].

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Borisova, N.E., Knizhnikov, V.A., Gulevich, T.G. et al. Pincer ligands based on α-amino acids: III. New ligands based on 4-substituted phenols and their copper complexes. Enantioselective recognition of tyrosine. Russ J Org Chem 45, 365–373 (2009). https://doi.org/10.1134/S107042800903004X

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  • DOI: https://doi.org/10.1134/S107042800903004X

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