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Methods and mechanisms of epoxy compounds reduction

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Abstract

Analysis was performed of reduction processes of epoxy derivatives obtained from unsaturated compounds belonging to various groups: alkenes, cycloalkenes, spiroalkanes, and substituted norbornenes. The regio- and stereochemistry was discussed of reactions between epoxides and complex metal hydrides, of catalytic hydrogenation, and some other processes. The mechanisms were considered of the reduction reactions, in particular, those involving radical and ion radical intermediates.

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Authors and Affiliations

  1. Dnepropetrovsk National University, Dnepropetrovsk, 49050, Ukraine

    L. I. Kas’yan

  2. ProBioGen AG, Berlin, Germany

    A. O. Kas’yan

  3. Kirovograd State Pedagogical University, Kirovograd, Ukraine

    E. A. Golodaeva

Authors
  1. L. I. Kas’yan
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  2. A. O. Kas’yan
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  3. E. A. Golodaeva
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Correspondence to L. I. Kas’yan.

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Original Russian Text © L.I. Kas’yan, A.O. Kas’yan, E.A. Golodaeva, 2008, published in Zhurnal Organicheskoi Khimii, 2008, Vol. 44, No. 2, pp. 167–194.

Kas’yan Liliya Ivanovna was born in the town Staryi Oskol, Belgorod Oblast’. She graduated from Odessa State University in 1960. Candidate of Chemical Sciences since 1970, Doctor of Chemical Sciences since 1990. Honored Worker of Science and Engineering of the Ukraine. Professor at the Chair of Organic Chemistry at the Dnepropetrovsk National University.

Field of scientific interests: chemistry of epoxy compounds, chemistry of cage-like compounds, mechanisms and stereochemistry of organic reactions.

Kas’yan Andrei Olegovich was born in 1966 in Dnepropetrovsk. In 1988 he graduated from Dnepropetrovsk State University. Candi-date of Chemical Sciences since 1993. In 1996–2002 worked in Universities of Halle and Aachen (Germany). At present he is the Head of Laboratory at the ProBioGen Co (Berlin).

Field of scientific interests: chemistry of cage-like compounds.

Golodaeva Elena Anatol’evna was born in 1977 in Sverdlovsk. In 1999 she graduated from Dnepropetrovsk State University. Candidate of Chemical Sciences since 2003. Assistant Professor of Kirovograd State Pedagogical University.

Field of scientific interests: chemistry of cagelike compounds.

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Kas’yan, L.I., Kas’yan, A.O. & Golodaeva, E.A. Methods and mechanisms of epoxy compounds reduction. Russ J Org Chem 44, 153–183 (2008). https://doi.org/10.1134/S1070428008020012

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