Abstract
Reactions of pyridine N-oxide with ethylenediamine and o- and p-phenylenediamines in the presence of p-toluenesulfonyl chloride in alkaline medium lead to the formation of the corresponding N,N′-bis-(p-tolylsulfonyl)-N,N′-bis(pyridin-2-yl)diamines as a result of reductive acylamination.
Similar content being viewed by others
References
Kurbatov, Yu.V. and Solekhova, M.A., Zh. Org. Khim., 1983, vol. 19, p. 663.
Kurbatov, Yu.V. and Solekhova, M.A., Khim. Geterotsikl. Soedin., 1986, p. 936.
Sharp, T.M., J. Chem. Soc., 1938, p. 1191.
Thomas, K. and Jerchel, D., FRG Patent Appl. no. 2606592, 1974; Chem. Abstr., 1977, vol. 87, no. 167891z.
Dictionary of Organic Compounds, Heilbron, J. and Bunbury, H.M., Eds., London: Eyre and Spottswoode, 1953, vol. 1.
Fischer, O., Ber., 1902, vol. 35, p. 3674.
Author information
Authors and Affiliations
Additional information
Original Russian Text © Yu.V. Kurbatov, M.A. Solekhova, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 11, pp. 1696–1697.
Rights and permissions
About this article
Cite this article
Kurbatov, Y.V., Solekhova, M.A. Reductive acylamination of pyridine N-oxide with ethylenediamine and phenylenediamines. Russ J Org Chem 43, 1696–1697 (2007). https://doi.org/10.1134/S1070428007110176
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1070428007110176