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Kinetics and mechanism of unimolecular heterolysis of framework compounds: XX. Solvation and steric effects in heterolysis of 2-halo-2-alkyladamantanes in sulfolane and butanol

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Abstract

Hetrolysis rate of 2-halo-2-phenyladamantanes in BuOH is 1000 times higher than the heterolysis rate of 2-halo-2-methyladamantanes. The heterolysis rate in sulfolane does not depend on the substituent, but the phenyl group exhibits a negative steric effect.

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Authors and Affiliations

  1. National Technical University of the Ukraine “Kiev Politechnical Institute”, Kiev, 03056, Ukraine

    G. F. Dvorko, A. I. Vasil’kevich, K. V. Mikhal’chuk & I. V. Koshchii

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  1. G. F. Dvorko
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  2. A. I. Vasil’kevich
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  3. K. V. Mikhal’chuk
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  4. I. V. Koshchii
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Additional information

Original Russian Text © G.F. Dvorko, A.I. Vasil’kevich, K.V. Mikhal’chuk, I.V. Koshchii, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 2, pp. 196–199.

For Communication XIX, see [1].

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Dvorko, G.F., Vasil’kevich, A.I., Mikhal’chuk, K.V. et al. Kinetics and mechanism of unimolecular heterolysis of framework compounds: XX. Solvation and steric effects in heterolysis of 2-halo-2-alkyladamantanes in sulfolane and butanol. Russ J Org Chem 43, 188–191 (2007). https://doi.org/10.1134/S1070428007020066

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  • DOI: https://doi.org/10.1134/S1070428007020066

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